Shilovite

Cu(NH3)4(NO3)2
IMA status
  • Approved
IMA symbol
Shil
IMA approved
2014
Also known as
  • IMA2014-016
  • Shiloviet

Where it forms, where it's found

Geological setting

Guano deposit hosted in a chalcopyrite bearing gabbro.

Type locality
Pabellón de Pica
  1. Chanabaya
  2. Iquique
  3. Iquique Province
  4. Tarapacá
  5. Chile

-20.9089°, -70.1381°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Deep violet blue
Streak
violet blue and becomes light blue as a result of decomposition and loss of NH3
Tenacity
sectile
Cleavage
None Observed
Density
1.92 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40 – 50° · 2V calc = 57°
Refractive index
1.527 – 1.61
Surface relief
Moderate
Principal indices
nα 1.527 · nβ 1.545 · nγ 1.610
Michel-Lévy diagramhighlighted lineδ = 0.0830
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]830 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation830 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnn2
Cell parameters
a = 23.6585(9) Å · b = 10.8238(4) Å · c = 6.9054(3) Å
Ratio a:b:c
1 : 0.458 : 0.292
Unit cell volume
1768.3 ų
Z
8
Morphology

Thick tabular to equant crystals up to 0.15 mm in size.

Type-locality form

Imperfect, thick tabular to equant crystals up to 0.15 mm in size included in massive halite.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
37.55%
7NNitrogenNitrogen614.00784.042
32.87%
29CuCopperCopper163.54663.546
24.85%
1HHydrogenHydrogen121.00812.096
4.73%
Total255.678100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • IMA2014-016
  • Shiloviet

In other languages

German
IMA 2014-016 · Shilovit
Italian
shilovite

Classification

Strunz
10th ed.

5.NA.25

  • 5CarbonatesClass
  • 5.NNITRATESDivision
  • 5.NAWithout OH or H2OGroup
  • 5.NA.25ShiloviteSpecies

Literature, links & citation

Citations
  1. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 21. Mineralogical Magazine, 78 (4) 797-804 doi:10.1180/minmag.2014.078.4.03DOI: 10.1180/minmag.2014.078.4.03
  2. 2015Chukanov, Nikita V., Britvin, Sergey N., Möhn, Gerhard, Pekov, Igor V., Zubkova, Natalia V., Nestola, Fabrizio, Kasatkin, Anatoly V., Dini, Maurizio (2015) Shilovite, natural copper(II) tetrammine nitrate, a new mineral species. Mineralogical Magazine, 79 (3) 613-623 doi:10.1180/minmag.2015.079.3.07 DOI: 10.1180/minmag.2015.079.3.07
  3. 2017(2017) Shilovite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Shilovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/shilovite-46139},
  note      = {Accessed 2026-05-11}
}