Sidwillite

MoO3 · 2H2O
IMA status
  • Approved
IMA symbol
Sdw
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-089
  • Sidwilliet

Where it forms, where it's found

Geological setting

quartz vein

Type locality
Lake Como
  1. San Juan County
  2. Colorado
  3. USA

37.9229°, -107.6249°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Canary-yellow

pleochroic, colorless - yellow at 47° ^ a-axis (Cesbron and Ginderow 1985)

Streak
pale yellow
Cleavage
Perfect

[010] (Cesbron and Ginderow 1985)

Density
3.12 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 48° · 2V calc = 48°
Refractive index
1.7 – 2.38
Surface relief
Very high
Principal indices
nα 1.70 · nβ 2.21 · nγ 2.38
Pleochroism
Strong

X = colorless; Y = Z = yellow.

Dispersion
relatively weak
Michel-Lévy diagramhighlighted lineδ = 0.6800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]6800 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation6800 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.618(5) Å · b = 13.825(7) Å · c = 10.482(5) Å
Cell angles
β = 91.61(4) °
Ratio a:b:c
1 : 1.302 : 0.987
Z
16
Comment

Space Group: P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
42MoMolybdenumMolybdenum195.95095.950
53.31%
8OOxygenOxygen515.99979.995
44.45%
1HHydrogenHydrogen41.0084.032
2.24%
Total179.977100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1983-089
  • Sidwilliet

In other languages

German
IMA 1983-089 · Sidwillit
Italian
Sidwillite

Classification

Strunz
10th ed.

4.FJ.05

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FJHydroxides with H2O +- (OH); corner-sharing octahedraGroup
  • 4.FJ.05SidwilliteSpecies
Dana
8th ed.

04.05.06.01

  • 04Simple OxidesClass
  • 04.05AX3Type
  • 04.05.06— unnamed intermediate level —Group
  • 04.05.06.01SidwilliteSpecies
CIM

7.15.3

  • 7Oxides and HydroxidesClass
  • 7.15Oxides of Mo and WGroup
  • 7.15.3SidwilliteSpecies

Literature, links & citation

Citations
  1. 1950Lindqvist, Ingvar, Hassel, O., Sillén, Lars Gunnar, Rottenberg, Max (1950) The Crystal Structure of the Yellow Molybdic Acid, MoO3.2H2O. On the Existence of an H4O2+ Ion. Acta Chemica Scandinavica, 4. 650-657 doi:10.3891/acta.chem.scand.04-0650DOI: 10.3891/acta.chem.scand.04-0650
  2. 1972Krebs, B. (1972) Die Kristallstruktur von MoO3.2H2O. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 28 (7) 2222-2231 doi:10.1107/s0567740872005849DOI: 10.1107/s0567740872005849
  3. 1985Cesbron, Fabien, Ginderow, Daria (1985) La sidwillite, MoO3·2H2O ; une nouvelle espèce minérale de Lake Como, Colorado, U.S.A. Bulletin de Minéralogie, 108 (6) 813-823 doi:10.3406/bulmi.1985.7899DOI: 10.3406/bulmi.1985.7899
  4. 1986Hawthorne, F.C., Bladh, K.W., Burke, E.A.J., Ercit, S., Grew, E.S., Grice, J.D., Puziewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 1543-1548.
  5. 1993Boudjada, N., Rodrı́guez-Carvajal, J., Anne, M., Figlarz, M. (1993) Dehydration of MoO3 · 2H2O: A Neutron Thermodiffractometry Study. Journal of Solid State Chemistry, 105. 211-222 doi:10.1006/jssc.1993.1209DOI: 10.1006/jssc.1993.1209
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sidwillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sidwillite-3654},
  note      = {Accessed 2026-05-11}
}