Siligiite

[Pb(H2O)5(SO4)][Zn9(OH)18]
IMA status
  • Approved
IMA symbol
Sigi
Also known as
  • Siligiiet

Where it forms, where it's found

Geological setting

vugs in massive galena-sphalerite-chalcopyrite-quartz in close association with secondary minerals

Type locality
Redmond Mine
  1. Waterville Lake
  2. Haywood County
  3. North Carolina
  4. USA

35.6802°, -83.0186°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
colorless
Tenacity
brittle
Cleavage
Perfect

two cleavages: perfect on (001) and good on (100)

Fracture
Splintery
Density
3.513 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50°
Refractive index
1.624 – 1.656
Surface relief
Moderate
Principal indices
nα 1.624 · nβ 1.650 · nγ 1.656
Dispersion
distinct r > v dispersion
Michel-Lévy diagramhighlighted lineδ = 0.0320
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]320 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation320 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 13.658(3) Å · b = 9.488(3) Å · c = 19.209(4) Å
Cell angles
β = 102.577(6) °
Ratio a:b:c
1 : 0.695 : 1.406
Z
4
Type-locality form

blades or flattened needles, up to about 1 mm long, with lengthwise striations, occurring in radiating clusters

Comment

P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc965.380588.420
45.69%
8OOxygenOxygen2715.999431.973
33.54%
82PbLeadLead1207.200207.200
16.09%
16SSulfurSulfur132.06032.060
2.49%
1HHydrogenHydrogen281.00828.224
2.19%
Total1287.877100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Siligiiet

In other languages

German
Siligiit

Classification

Strunz
10th ed.

7.DF

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DFSiligiiteSpecies

Literature, links & citation

Citations
  1. Kampf, A. R., Smith, J. B., Hughes, J. M., Ma, C., and Emproto, C.: Siligiite, IMA 2023-117, in: CNMNC Newsletter 78, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-361-2024, 2024.
  2. 2024Kampf, Anthony R.; Smith, Jason B.; Hughes, John M.; Ma, Chi; Emproto, Christopher (2024) New Minerals from the Redmond Mine, North Carolina, USA: IX. Siligiite, a Lead-Zinc Sulfate with a Novel Heteropolyhedral Sheet. The Canadian Journal of Mineralogy and Petrology, 62 (6). 881-889 doi:10.3749/2400020DOI: 10.3749/2400020
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Siligiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/siligiite-471062},
  note      = {Accessed 2026-05-11}
}