Silinaite

NaLiSi2O5 · 2H2O
IMA status
  • Approved
IMA symbol
Sln
Discovered
1990
IMA approved
1990
Also known as
  • IMA1990-028
  • Silinaiet
  • Unnamed (MSH UK-81)

Where it forms, where it's found

Geological setting

In sodalite syenite xenoliths in nepheline syenite.

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Colourless · white
Streak
White
Tenacity
brittle
Cleavage
Perfect

(001) perfect, (010) good, and (110) distinct

Fracture
Conchoidal
Density
2.24 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 64 – 71° · 2V calc = 72°
Refractive index
1.515 – 1.518
Surface relief
Moderate
Principal indices
nα 1.515 · nβ 1.516 · nγ 1.518
Pleochroism
Non-pleochroic
Dispersion
strong, r > v
Extinction
X = b; Y ∧ c = 16° in the acute β angle
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.061 Å · b = 8.334 Å · c = 14.383 Å
Cell angles
β = 96.67 °
Ratio a:b:c
1 : 1.647 : 2.842
Unit cell volume
602.55 ų
Z
4
Type-locality form

Clear tabular crystals up to 2 mm, fibrous clusters, poorly formed prismatic crystals, and chalky to earthy or powdery patches.

Comment

cell param. A2/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
55.41%
14SiSiliconSilicon228.08556.170
27.79%
11NaSodiumSodium122.99022.990
11.37%
3LiLithiumLithium16.9406.940
3.43%
1HHydrogenHydrogen41.0084.032
2.00%
Total202.125100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Ca

Synonyms

  • IMA1990-028
  • Silinaiet
  • Unnamed (MSH UK-81)

In other languages

German
IMA 1990-028 · Silinait
Italian
Silinaite

Classification

Strunz
10th ed.

9.EF.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EFSingle nets with 6-membered rings, connected by M[4], M[8], etc.Group
  • 9.EF.20SilinaiteSpecies
Dana
8th ed.

74.03.05.03

  • 74Phyllosilicates Modulated LayersClass
  • 74.03Modulated Layers with joined stripsType
  • 74.03.05Na phyllosilicatesGroup
  • 74.03.05.03SilinaiteSpecies
CIM

14.1.8

  • 14Silicates not Containing AluminumClass
  • 14.1Silicates of the alkali metalsGroup
  • 14.1.8SilinaiteSpecies

Literature, links & citation

Citations
  1. 1991Chao, George Y., Grice, Joel D., Gault, Robert A. (1991) Silinaite, a new sodium lithium silicate hydrate mineral from Mont Saint-Hilaire, Quebec. The Canadian Mineralogist, 29 (2) 359-362
  2. 1991Grice, J. D. (1991) The crystal structure of silinaite, NaLiSi2O5·2H2O: a monophyllosilicate. The Canadian Mineralogist, 29 (2) 363-367
  3. 1995Beneke, Klaus, Thiesen, Peter, Lagaly, Gerhard (1995) Synthesis and Properties of the Sodium Lithium Silicate Silinaite. Inorganic Chemistry, 34 (4) 900-907 doi:10.1021/ic00108a022DOI: 10.1021/ic00108a022
  4. 1999Huang, Yining, Jiang, Zhimei, Schwieger, Wilhelm (1999) A structural investigation of the singly layered silicates, silinaite and makatite, by vibrational spectroscopy. Canadian Journal of Chemistry, 77 (4). 495-501 doi:10.1139/cjc-77-4-495DOI: 10.1139/cjc-77-4-495
  5. 2001(2001) Silinaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Silinaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/silinaite-3661},
  note      = {Accessed 2026-05-11}
}