Sitinakite

KNa2Ti4Si2O13(OH) · 4H2O
IMA status
  • Approved
IMA symbol
Sit
Discovered
1989
IMA approved
1989
Also known as
  • IMA1989-051
  • Sitinakiet

Where it forms, where it's found

Geological setting

In hydrothermal natrolite nodules in alkalic pegmatites.

Type locality
Yukspor Mountain
  1. Murmansk Oblast
  2. Russia

67.6731°, 33.8122°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · light-brown to pale rose · pinkish brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

(100) and (001)

Density
2.86 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.78 – 1.988
Surface relief
Very high
Principal indices
nω 1.780 · nε 1.988
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.2080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2080 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2080 nm
Order4th order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
P42/mcm
Cell parameters
a = 7.819(2) Å · c = 12.099(4) Å
Z
2
Type-locality form

Equant and short prismatic crystals, 1 x 1 x 2 mm, and in 3-4 mm patches of intergrown crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
45.73%
22TiTitaniumTitanium447.867191.468
30.40%
14SiSiliconSilicon228.08556.170
8.92%
11NaSodiumSodium222.99045.980
7.30%
19KPotassiumPotassium139.09839.098
6.21%
1HHydrogenHydrogen91.0089.072
1.44%
Total629.770100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • Sr
  • Ba
  • Ce
  • Fe
  • Nb
  • Ta
  • Zr
  • TR

Synonyms

  • IMA1989-051
  • Sitinakiet

In other languages

German
IMA 1989-051 · Sitinakit
Italian
Sitinakite

Classification

Strunz
10th ed.

9.AG.30

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AGNesosilicates with additional anions; cations in > [6] +- [6] coordinationGroup
  • 9.AG.30SitinakiteSpecies
Dana
8th ed.

52.04.11.01

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.04Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordinationType
  • 52.04.11— unnamed intermediate level —Group
  • 52.04.11.01SitinakiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. Panikorovskii, T.L. , Yakovenchuk, V.N., Kalashnikova, G.O., Bazai, A.V., Ikkonen, P., Yanicheva N.Yu., Krivovichev, S.V. (2023): Microporous sorbents for Th4+, REE3+, Cs+. Trudy Fersmanovskoy nauchnoy sessii GI KNTS RAN, 20, 632-638.
  2. 1989Sokolova, E.V., Rastsvetaeva, R.K., Andrianov, V.I., Egorov-Tismenko, Y.K., Men'shikov, Y.P. (1989) The crystal structure of a new sodium titanosilicate. Soviet Physics - Doklady, 34, 583-585.
  3. 1992Men´shikov, Y. P., Sokolova, E. V., Egorov-Tismenko, Y. K., Khomyakov, A. P., Polezhaeva, L. I. (1992) Sitinakite Na2KTi4Si2O13(OH)·4H2O - a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 121 (1) 94-99
  4. 1993Jambor, John L., Vanko, David A. (1993) New Mineral Names. American Mineralogist, 78 (11-12) 1314-1319
  5. 1994Poojary, D.M., Cahill, R.A., Clearfield, A. (1994) Synthesis, Crystal Structures, and Ion-Exchange Properties of a Novel Porous Titanosilicate. Chemistry of Materials, 6, 2364–2368.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sitinakite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sitinakite-3677},
  note      = {Accessed 2026-05-11}
}