Skorpionite

Ca3Zn2(PO4)2(CO3)(OH)2 · H2O
IMA status
  • Approved
IMA symbol
Skr
IMA approved
2005
Also known as
  • IMA2005-010
  • Skorpioniet

Where it forms, where it's found

Geological setting

Non-sulphide, zinc deposit formed by supergene oxidation.

Type locality
Skorpion Mine
  1. Rosh Pinah
  2. Oranjemund Constituency
  3. ǁKaras Region
  4. Namibia

-27.8180°, 16.5976°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colourless
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.15 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 15.0°
Refractive index
1.5884 – 1.6455
Surface relief
Moderate
Principal indices
nα 1.5884 · nβ 1.6445 · nγ 1.6455
Dispersion
None
Extinction
Y^c = 26◦ (in the acute angle β); Z = b.
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0571
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]571 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation571 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 19.042(2) Å · b = 9.309(1) Å · c = 6.519(1) Å
Cell angles
β = 92.72(1) °
Ratio a:b:c
1 : 0.489 : 0.342
Unit cell volume
1154.3 ų
Z
4
Morphology

Bladed, sword-shaped. Type material: crystals are elongated parallel to [001] with dominant (100) and (110); additional forms are (111), (221), (131) and (101).

Twinning

None observed

Type-locality form

Colourless needle-like crystals elongated parallel to [001].

Comment

refined from X-ray powder data

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
40.51%
30ZnZincZinc265.380130.760
23.65%
20CaCalciumCalcium340.078120.234
21.74%
15PPhosphorusPhosphorus230.97461.948
11.20%
6CCarbonCarbon112.01112.011
2.17%
1HHydrogenHydrogen41.0084.032
0.73%
Total552.971100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-010
  • Skorpioniet

In other languages

German
IMA 2005-010 · Skorpionit
Italian
skorpionite

Classification

Strunz
10th ed.

8.DO.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DOWith CO3, SO4, SiO4Group
  • 8.DO.45SkorpioniteSpecies
Dana
8th ed.

43.05.20

  • 43Compound Phosphates, Etc.Class
  • 43.05Hydrated Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.05.20— unnamed intermediate level —Group
  • 43.05.20SkorpioniteSpecies

Literature, links & citation

Citations
  1. 2003Borg, G., Karner, K., Buxton, M., Armstrong, R., Merwe, S. W. v. d. (2003) Geology of the Skorpion Supergene Zinc Deposit, Southern Namibia. Economic Geology, 98 (4) 749-771 doi:10.2113/gsecongeo.98.4.749DOI: 10.2113/gsecongeo.98.4.749
  2. 2007Jahn, S. (2007): Tarbuttit von der Skorpion Zink Mine, Namibia. Mineralien-Welt 18 (4), 56-66. (in German)
  3. 2008Krause, Werner, Effenberger, Herta, Bernhardt, Heinz-Jürgen, Medenbach, Olaf (2008) Skorpionite, Ca3Zn2(PO4)2CO3(OH)2H2O, a new mineral from Namibia: description and crystal structure. European Journal of Mineralogy, 20 (2) 271-280 doi:10.1127/0935-1221/2008/0020-1789 DOI: 10.1127/0935-1221/2008/0020-1789
  4. 2009Poirier, G., Ercit, T. S., Tait, K. T., Piilonen, P. C., Rowe, R. (2009) New Mineral Names. American Mineralogist, 94 (2) 399-408 doi:10.2138/am.2009.538DOI: 10.2138/am.2009.538
  5. 2011(2011) Skorpionite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Skorpionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/skorpionite-27395},
  note      = {Accessed 2026-05-11}
}