Smirnite

Bi3+2Te4+O5
IMA status
  • Approved
IMA symbol
Smr
Discovered
1982
IMA approved
1982
Also known as
  • IMA1982-104
  • Smirniet

Where it forms, where it's found

Geological setting

Occurs in fractures of vein quartz and chalcedony, containing the relics of tellurobismuthite, tetradymite, volynskite and galena.

Oxidation zone of tellurium bearing hydrothermal ore deposits.

Type locality
Sotk gold mine
  1. Sotk
  2. Gegharkunik Province
  3. Armenia

40.2330°, 45.9680°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · gray · light yellow

Darkens on exposure to sunlight

Tenacity
brittle
Cleavage
Perfect

Perfect on (010) Distinct in other directions

Density
7.78 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 35 – 40° · 2V calc = 38°
Refractive index
2.35 – 2.46
Surface relief
Very high
Principal indices
nα 2.35 · nβ 2.36 · nγ 2.46
Dispersion
none
Extinction
Straight extinction.
Anisotropism
Strong
Tropism
Anisotropic
Reflectance R%
(20.7,19.1) 400, (20.5,18.8) 420, (20.0,18.1) 440, (19.7,17.8) 460, (19.4,17.5) 480, (19.3,17.5) 500, (19.3,17.4) 520, (19.2,17.4) 540, (19.1,17.3) 560, (19.0,17.2) 580, (18.8,17.0) 600, (18.7,16.8) 620, (18.5,16.7) 640, (18.3,16.5) 660, (18.2,16.3) 680, (18.0,16.3) 700
Notes

Z = a, Y = b, X = c

Reflected-light panel
19.2 %anisotropic · dual curve
Specimen sRGB 160, 112, 62
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 16.447(19) Å · b = 5.513(3) Å · c = 11.579(15) Å
Ratio a:b:c
1 : 0.335 : 0.704
Z
8
Morphology

Crystals tabular to 2mm, aggregates and incrustations.

Type-locality form

Tabular crystals up to 2 mm and aggregates, or crusts on quartz and tellurides.

Comment

Space Group: Cm2a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2208.980417.960
66.81%
52TeTelluriumTellurium1127.600127.600
20.40%
8OOxygenOxygen515.99979.995
12.79%
Total625.555100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1982-104
  • Smirniet

In other languages

German
IMA 1982-104 · Smirnit
Italian
Smirnite

Classification

Strunz
10th ed.

4.JK.40

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JKTellurites without additional anions, without H2OGroup
  • 4.JK.40SmirniteSpecies
Dana
8th ed.

34.01.08.01

  • 34Selenites, Tellurites and SulfitesClass
  • 34.01A(XO3)Type
  • 34.01.08— unnamed intermediate level —Group
  • 34.01.08.01SmirniteSpecies
CIM

28.3.16

  • 28Selenites, Selenates, Tellurites, and TelluratesClass
  • 28.3TelluritesGroup
  • 28.3.16SmirniteSpecies

Literature, links & citation

Citations
  1. 1983Mercurio, D., El Farissi, M., Frit, B., Goursat, P. (1983) Etude structurale et densification d'un nouveau materiau piezoelectrique: Bi2TeO5. Materials Chemistry and Physics: 9: 467-476.
  2. 1984Spiridonov, E.M., Demina, L.A., Dolgikh, V.A., Antonina, G.M., Rakcheev, A.D., Bulgak, L.V., Lebedeva, S.I., Chvileva, T.N. (1984) Smirnite Bi2TeO5 - a new mineral. Doklady Akademii Nauk SSSR: 278: 199-202.
  3. 1985Dunn, Pete J., Fleischer, Michael, Langley, Richard H., Shigley, James E., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (7-8) 871-881
  4. 2005(2005) Smirnite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2019López, C.A., Bâati, E., Fernández-Díaz, M.T., Saouma, F.O., Jang, J.J., Alonso, J.A. (2019) Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data. Journal of Solid State Chemistry: 276: 122-127.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Smirnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/smirnite-3686},
  note      = {Accessed 2026-05-11}
}