Where it forms, where it's found
- Type locality
- Lengenbach Quarry
- Fäld
- Binn
- Goms
- Valais
- Switzerland
46.3653°, 8.2205°
11recorded occurrences
Safety & handling
Physical
Optical
- Optical type
- Biaxial (-) · 2V measured = 65°
- Refractive index
- 3.27
- Surface relief
- Very high
- Principal indices
- nβ 3.27
- Pleochroism
- Weak
Slight in transmitted light.
- Dispersion
- marked to extreme
- Extinction
- Y = b; Z ∧ c = 6.5°.
- Tropism
- Anisotropic
- Reflectance R%
- (40.7,44.0) 400, (40.0,43.2) 420, (39.3,42.4) 440, (38.7,41.5) 460, (37.9,40.4) 480, (37.0,39.2) 500, (36.0,38.0) 520, (35.0,36.6) 540, (33.8,35.4) 560, (32.7,34.7) 580, (32.0,34.0) 600, (31.4,33.4) 620, (31.0,32.9) 640, (30.6,32.4) 660, (30.4,31.8) 680, (30.1,31.4) 700
Reflected-light panel
R̄ 34.8 %anisotropic · dual curve
Specimen
White reference
R₁ R₂
Mode
Crystallography
- Cell parameters
- a = 17.23 Å · b = 7.78 Å · c = 15.19 Å
- Cell angles
- β = 101.2 °
- Ratio a:b:c
- 1 : 0.452 : 0.882
- Z
- 24
- Morphology
Equant; tabular (100). Tabular crystals appear hexagonal due to strong zonal developments nearly 60° apart.
- Comment
Space Group: A2/a.
Crystal structure
Chemical composition
Synonyms
- Arsenmiargyrit (nach Jaeger und van Klooster)
- Arsenomiargyrite (of Jaeger and van Klooster)
- Smithiet
In other languages
- French
- Smithite
- German
- Smithit
- Italian
- Smithite
Classification
Strunz
10th ed.2.GC.30
- 2Sulfides and SulfosaltsClass
- 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
- 2.GCPoly-sulfarsenitesGroup
- 2.GC.30SmithiteSpecies
Dana
8th ed.03.07.03.01
- 03SulfosaltsClass
- 03.07ø = 2Type
- 03.07.03— unnamed intermediate level —Group
- 03.07.03.01SmithiteSpecies
CIM
—5.2.1
- 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
- 5.2Sulpharsenites etc. of AgGroup
- 5.2.1SmithiteSpecies
Group, growth & confusion
Literature, links & citation
Citations
- 1905Solly, R. H. (1905) Some new minerals from the Binnenthal, Switzerland. Mineralogical Magazine and Journal of the Mineralogical Society, 14 (64) 72-82 doi:10.1180/minmag.1905.014.64.03 DOI: 10.1180/minmag.1905.014.64.03
- 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
- 1962Geological Society of America Memoir 85 (1962): 142.
- 1964Hellner, E., Burzlaff, H. (1964) Die Struktur des Smithits AgAsS2. Die Naturwissenschaften, 51 (2). 35-36 doi:10.1007/bf00622577DOI: 10.1007/bf00622577
- 1968Wehmeier, F.H.; Laudise, R.A.; Shiever, J.W. (1968) The system Ag2S-As2S3 and the growth of crystals of proustite, smithite and pyrargyrite. Materials Research Bulletin, 3 (9). 767-777 doi:10.1016/0025-5408(68)90046-9DOI: 10.1016/0025-5408(68)90046-9
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Smithite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/smithite-3687},
note = {Accessed 2026-05-11}
}