Smithite

AgAsS2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sth
Discovered
1905
Also known as
  • Arsenmiargyrit (nach Jaeger und van Klooster)
  • Arsenomiargyrite (of Jaeger and van Klooster)
  • Smithiet

Where it forms, where it's found

Type locality
Lengenbach Quarry
  1. Fäld
  2. Binn
  3. Goms
  4. Valais
  5. Switzerland

46.3653°, 8.2205°

11recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Pale red · red-orange or brownish orange on exposure to light
Streak
Vermillion
Tenacity
brittle
Cleavage
Perfect

(100) perfect

Fracture
Conchoidal
Density
4.88 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 65°
Refractive index
3.27
Surface relief
Very high
Principal indices
nβ 3.27
Pleochroism
Weak

Slight in transmitted light.

Dispersion
marked to extreme
Extinction
Y = b; Z ∧ c = 6.5°.
Tropism
Anisotropic
Reflectance R%
(40.7,44.0) 400, (40.0,43.2) 420, (39.3,42.4) 440, (38.7,41.5) 460, (37.9,40.4) 480, (37.0,39.2) 500, (36.0,38.0) 520, (35.0,36.6) 540, (33.8,35.4) 560, (32.7,34.7) 580, (32.0,34.0) 600, (31.4,33.4) 620, (31.0,32.9) 640, (30.6,32.4) 660, (30.4,31.8) 680, (30.1,31.4) 700
Reflected-light panel
34.8 %anisotropic · dual curve
Specimen sRGB 201, 147, 88
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 17.23 Å · b = 7.78 Å · c = 15.19 Å
Cell angles
β = 101.2 °
Ratio a:b:c
1 : 0.452 : 0.882
Z
24
Morphology

Equant; tabular (100). Tabular crystals appear hexagonal due to strong zonal developments nearly 60° apart.

Comment

Space Group: A2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver1107.868107.868
43.69%
33AsArsenicArsenic174.92274.922
30.34%
16SSulfurSulfur232.06064.120
25.97%
Total246.910100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sb

Synonyms

  • Arsenmiargyrit (nach Jaeger und van Klooster)
  • Arsenomiargyrite (of Jaeger and van Klooster)
  • Smithiet

In other languages

French
Smithite
German
Smithit
Italian
Smithite

Classification

Strunz
10th ed.

2.GC.30

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GCPoly-sulfarsenitesGroup
  • 2.GC.30SmithiteSpecies
Dana
8th ed.

03.07.03.01

  • 03SulfosaltsClass
  • 03.07ø = 2Type
  • 03.07.03— unnamed intermediate level —Group
  • 03.07.03.01SmithiteSpecies
CIM

5.2.1

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.1SmithiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1905Solly, R. H. (1905) Some new minerals from the Binnenthal, Switzerland. Mineralogical Magazine and Journal of the Mineralogical Society, 14 (64) 72-82 doi:10.1180/minmag.1905.014.64.03 DOI: 10.1180/minmag.1905.014.64.03
  2. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  3. 1962Geological Society of America Memoir 85 (1962): 142.
  4. 1964Hellner, E., Burzlaff, H. (1964) Die Struktur des Smithits AgAsS2. Die Naturwissenschaften, 51 (2). 35-36 doi:10.1007/bf00622577DOI: 10.1007/bf00622577
  5. 1968Wehmeier, F.H.; Laudise, R.A.; Shiever, J.W. (1968) The system Ag2S-As2S3 and the growth of crystals of proustite, smithite and pyrargyrite. Materials Research Bulletin, 3 (9). 767-777 doi:10.1016/0025-5408(68)90046-9DOI: 10.1016/0025-5408(68)90046-9
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Smithite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/smithite-3687},
  note      = {Accessed 2026-05-11}
}