Sphaerobismoite

Bi2O3
IMA status
  • Approved
IMA symbol
Sbm
IMA approved
1993
Also known as
  • IMA1993-009
  • Sphaerobismoiet
  • Sphaerobismoita

Where it forms, where it's found

Geological setting

Oxidation product of wittichenite and emplectite.

Type locality
Neubulach
  1. Calw
  2. Karlsruhe Region
  3. Baden-Württemberg
  4. Germany
5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Subadamantine
Transparency
Transparent
Colour
Green · pale yellow · gray

Semitransparent

Streak
White
Fracture
Conchoidal
Density
7.17 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.13 – 2.18
Surface relief
Very high
Principal indices
nω 2.13 · nε 2.18
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 8.02(2) Å · c = 6.46(2) Å
Z
4
Type-locality form

Tabular, crystals to 20 µm, tetragonal outline possible, forming spherulitic aggregates.

Comment

Space group P42/n or P42212. Synthetic material is reported to have space group P-421c (Blower & Greaves, 1988).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2208.980417.960
89.70%
8OOxygenOxygen315.99947.997
10.30%
Total465.957100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As

Synonyms

  • IMA1993-009
  • Sphaerobismoiet
  • Sphaerobismoita

In other languages

German
IMA 1993-009 · Sphaerobismoit
Italian
Sphaerobismoite

Classification

Strunz
10th ed.

4.CB.65

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.65SphaerobismoiteSpecies
Dana
8th ed.

04.03.13.01

  • 04Simple OxidesClass
  • 04.03A2X3Type
  • 04.03.13— unnamed intermediate level —Group
  • 04.03.13.01SphaerobismoiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1964Gattow, G., Sch�tze, D. (1964) �ber Wismutoxide. VI. �berein Wismut (III)-oxid mit h�herem Sauerstoffgehalt (?-Modifikation) Zeitschrift f�r anorganische und allgemeine Chemie, 328 (1) 44-68 doi:10.1002/zaac.19643280106DOI: 10.1002/zaac.19643280106
  2. 1979Walenta, K. (1979) Die Sekundärmineralien der Erzgänge von Neubulach im nördlichen Schwarzwald [The secondary minerals of the ore veins of Neubulach in the northern Black Forest]. Der Aufschluss, 30 (7). 213-252
  3. 1988Blower, S. K., Greaves, C. (1988) The structure of β-Bi2O3 from powder neutron diffraction data. Acta Crystallographica Section C Crystal Structure Communications, 44 (4) 587-589 doi:10.1107/s0108270187011661DOI: 10.1107/s0108270187011661
  4. 1995Walenta, K. (1995): Sphaerobismoite, a new mineral of composition Bi2O3 from the Schwarzwald. Aufschluss: 46: 245-248. (in German).
  5. 1997Mandarino, Joseph A. (1997) Abstracts of New Mineral Descriptions. The Mineralogical Record, 28 (3) 219-224
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sphaerobismoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sphaerobismoite-7308},
  note      = {Accessed 2026-05-11}
}