Stergiouite

CaZn2(AsO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Sgo
IMA approved
2019
Also known as
  • IMA2018-051a
  • Stergiouiet

Where it forms, where it's found

Geological setting

Oxidation of sphalerite and native arsenic and dissolution of surrounding calcite.

Type locality
Plaka Mine No. 80
  1. Plaka Mines
  2. Plaka
  3. Lavreotiki
  4. East Attica
  5. Attica
  6. Greece

37.7552°, 24.0318°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
White to colourless
Streak
White
Tenacity
brittle
Cleavage
Perfect

(100)

Fracture
Irregular/Uneven
Density
3.1 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.561 – 1.621
Surface relief
Moderate
Principal indices
nα 1.561 · nβ 1.619 · nγ 1.621
Pleochroism
Not Visible
Dispersion
Very weak, with n(red) < n(violet).
Extinction
α is oriented approx. perpendicular to (100). β is parallel to [010].
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]600 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation600 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Pc
Cell parameters
a = 9.4160(3) Å · b = 5.3000(3) Å · c = 10.8931(4) Å
Cell angles
β = 91.767(1) °
Ratio a:b:c
1 : 0.563 : 1.157
Z
2
Morphology

The forms (100), (100) are dominant, (010), (001), (001), (101), (101), (101) and (101) are subordinate.

Twinning

Type material - no twinning was observed but inversion twinning is inferred from the X-ray structure refinement.

Type-locality form

Clusters of stacked, platy crystals. Individual plates rarely exceed 200 × 100 × 5 μm in size.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
36.87%
33AsArsenicArsenic274.922149.844
28.77%
30ZnZincZinc265.380130.760
25.11%
20CaCalciumCalcium140.07840.078
7.70%
1HHydrogenHydrogen81.0088.064
1.55%
Total520.734100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-051a
  • Stergiouiet

In other languages

German
IMA 2018-051a · Stergiouit · Stergiouite

Classification

Strunz
10th ed.

8.CA.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.75StergiouiteSpecies

Literature, links & citation

Citations
  1. 2019Miyawaki, Ritsuro, Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 47. European Journal of Mineralogy, 31 (1) 197-202 doi:10.1127/ejm/2019/0031-2839DOI: 10.1127/ejm/2019/0031-2839
  2. 2020Rieck, Branko, Giester, Gerald, Lengauer, Christian L., Chanmuang N., Chutimun, Topa, Dan (2020) Stergiouite, CaZn2(AsO4)2·4H2O – a new mineral from the Lavrion Mining District, Greece. Mineralogy and Petrology, 114 (4) 319-327 doi:10.1007/s00710-020-00702-2 DOI: 10.1007/s00710-020-00702-2
  3. 2022(2022) Stergiouite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Stergiouite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/stergiouite-53372},
  note      = {Accessed 2026-05-11}
}