Tancoite

LiNa2Al(PO4)(PO3OH)(OH)
IMA status
  • Approved
IMA symbol
Tco
Discovered
1979
IMA approved
1979
Also known as
  • IMA1979-045
  • Tancoiet

Where it forms, where it's found

Geological setting

LCA granite pegmatite.

Type locality
Tanco Mine
  1. Bernic Lake
  2. Lac-du-Bonnet area
  3. Manitoba
  4. Canada

50.4300°, -95.4464°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless to light pink
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

(010) and (100)

Fracture
Conchoidal · Sub-Conchoidal
Density
2.752 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 23° · 2V calc = 24°
Refractive index
1.541 – 1.564
Surface relief
Moderate
Principal indices
nα 1.541 · nβ 1.563 · nγ 1.564
Birefringence
0.023
Pleochroism
Non-pleochroic
Dispersion
r<v weak
Extinction
XYZ = cba
Michel-Lévy diagramhighlighted lineδ = 0.0230
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]230 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation230 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#61
Cell parameters
a = 14.08 Å · b = 14.13 Å · c = 6.97 Å
Ratio a:b:c
1 : 1.004 : 0.495
Z
8
Type-locality form

Isolated crystals up to 1 mm in length and as druses of columnar individuals, oriented subparallel to [001].

Comment

Pbcb

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
50.02%
15PPhosphorusPhosphorus230.97461.948
21.52%
11NaSodiumSodium222.99045.980
15.97%
13AlAluminiumAluminium126.98226.982
9.38%
3LiLithiumLithium16.9406.940
2.41%
1HHydrogenHydrogen21.0082.016
0.70%
Total287.857100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1979-045
  • Tancoiet

In other languages

German
IMA 1979-045 · Tancoit
Italian
Tancoite

Classification

Strunz
10th ed.

8.BG.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BGWith medium-sized and large cations, (OH, etc.):RO4 = 0.5:1Group
  • 8.BG.15TancoiteSpecies
Dana
8th ed.

41.04.07.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.07— unnamed intermediate level —Group
  • 41.04.07.01TancoiteSpecies
CIM

19.8.4

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.4TancoiteSpecies

Literature, links & citation

Citations
  1. 1980Ramik, R. A., Sturman, B. D., Dunn, P. J., Povarennykh, A. S. (1980) Tancoite, a new lithium sodium aluminum phosphate from the Tanco pegmatite, Bernic Lake, Manitoba. The Canadian Mineralogist, 18 (2) 185-190
  2. 1983Hawthorne, F. C. (1983) The crystal structure of tancoite. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 31 (1). 121-135 doi:10.1007/bf01084765DOI: 10.1007/bf01084765
  3. 2005(2005) Tancoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tancoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tancoite-3879},
  note      = {Accessed 2026-05-11}
}