Tennantite-(Cu)

Cu6(Cu4Cu2)As4S13
IMA status
  • Approved
IMA symbol
Tnt-Cu
IMA approved
2021
Also known as
  • "Cu-excess" tennantite
  • IMA2020-096
  • Tennantiet-(Cu)

Where it forms, where it's found

Geological setting

Epithermal deposit.

Type locality
Layo deposit
  1. Chachas District
  2. Castilla Province
  3. Arequipa
  4. Peru

-15.1878°, -72.2417°

18recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Streak
Black
Tenacity
brittle
Cleavage
Poor/Indistinct
Fracture
Conchoidal
Density
4.656 g/cm³

Optical

Optical colour
Grey with bluish shade
Tropism
Isotropic
Reflectance R%
(30.7) 400, (30.4) 420, (30.0) 440, (29.3) 460, (29.1) 470, (28.9) 480, (28.7) 500, (28.6) 520, (28.4) 540, (28.4) 546, (28.2) 560, (27.7) 580, (27.4) 589, (27.0) 600, (26.2) 620, (25.4) 640, (25.0) 650, (24.6) 660, (23.9) 680, (23.4) 700
Reflected-light panel
27.6 %isotropic · single curve
Specimen sRGB 186, 134, 76
White reference100 % reflector under same lamp
Reflected colour
Grey with bluish shade

Crystallography

Crystal system
Isometric
Space group
I-4 3m
Cell parameters
a = 10.1710(10) Å
Z
2
Type-locality form

Anhedral grains, up to 0.1 mm across.

Comment

For natural "copper-rich unsubstituted tennantite, Cu12.5As4S13", from Argentina, Makovicky et al. (2005) give a = 10.1756 Å.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1263.546762.552
51.56%
16SSulfurSulfur1332.060416.780
28.18%
33AsArsenicArsenic474.922299.688
20.26%
Total1479.020100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • "Cu-excess" tennantite
  • IMA2020-096
  • Tennantiet-(Cu)

In other languages

German
IMA 2020-096 · Tennantit-(Cu)
Italian
Tennantite- · Tennantite-(Cu)

Classification

Strunz
10th ed.

2.GB

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GBNeso-sulfarsenites, etc. with additional SGroup
  • 2.GBTennantite-(Cu)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 1985Cesbron, Fabien, Giraud, Roger, Picot, Paul, Pillard, François (1985) La vinciennite, Cu10Fe4Sn(As,Sb)S16, une nouvelle espèce minérale. Etude paragénétique du gîte type de Chizeuil, Saône-et-Loire. Bulletin de Minéralogie, 108 (3) 447-456 doi:10.3406/bulmi.1985.7841DOI: 10.3406/bulmi.1985.7841
  2. 1994Marcoux, E., Milési, J. P., Moëlo, Y. (1994) Vinciennite and Cu-excess tennantite from the Layo (Cu, Sn, As, Au) epithermal deposit (Southern Peru) Mineralogy and Petrology, 51 (1) 21-36 doi:10.1007/bf01164912DOI: 10.1007/bf01164912
  3. 2005Makovicky, E., Karanović, L., Poleti, D., Balić-Zunić, T., Paar, W. H. (2005) Crystal structure of copper-rich unsubstituted tennantite, Cu12.5As4S13. The Canadian Mineralogist, 43 (2) 679-688 doi:10.2113/gscanmin.43.2.679 DOI: 10.2113/gscanmin.43.2.679
  4. 2005Di Benedetto, F., Bernardini, G. P., Cipriani, C., Emiliani, C., Gatteschi, D., Romanelli, M. (2005) The distribution of Cu(II) and the magnetic properties of the synthetic analogue of tetrahedrite: Cu12Sb4S13. Physics and Chemistry of Minerals, 32 (3) 155-164 doi:10.1007/s00269-005-0449-8DOI: 10.1007/s00269-005-0449-8
  5. 2012Catchpole, H., Kouzmanov, K., Fontboté, L. (2012) Copper-excess stannoidite and tennantite-tetrahedrite as proxies for hydrothermal fluid evolution in a zoned Cordillerian base metal district, Morococha, Central Peru. The Canadian Mineralogist, 50 (3). 719-743 doi:10.3749/canmin.50.3.719DOI: 10.3749/canmin.50.3.719
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tennantite-(Cu) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tennantite-cu-55386},
  note      = {Accessed 2026-05-11}
}