Thebaite-(NH4)

(NH4)3Al(C2O4)(PO3OH)2(H2O)
IMA status
  • Approved
IMA symbol
Thb-NH4
IMA approved
2020
Also known as
  • IMA2020-072
  • Thebaiet-(NH4)

Where it forms, where it's found

Geological setting

Associated with bat guano.

Type locality
125 foot level
  1. Rowley Mine
  2. Theba
  3. Painted Rock Mining District
  4. Painted Rock Mountains
  5. Maricopa County
  6. Arizona
  7. USA

33.0492°, -113.0330°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Two good cleavages in the [010] zone, probably (100) and (102).

Fracture
Splintery
Density
2.093 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 82.7°
Refractive index
1.49 – 1.57
Surface relief
Moderate
Principal indices
nα 1.490 · nβ 1.534 · nγ 1.570
Dispersion
slight r > v dispersion
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 11.156(9) Å · b = 6.234(6) Å · c = 18.65(2) Å
Cell angles
β = 102.93(1) °
Ratio a:b:c
1 : 0.559 : 1.672
Z
4
Type-locality form

Blades up to ~0.1 mm in length.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
54.87%
15PPhosphorusPhosphorus230.97461.948
16.34%
7NNitrogenNitrogen314.00742.021
11.08%
13AlAluminiumAluminium126.98226.982
7.12%
6CCarbonCarbon212.01124.022
6.34%
1HHydrogenHydrogen161.00816.128
4.25%
Total379.088100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2020-072
  • Thebaiet-(NH4)

In other languages

German
IMA 2020-072 · Thebait-(NH4)
Italian
Thebaite- · Thebaite-(NH4)

Classification

Strunz
10th ed.

8.DH

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DHThebaite-(NH4)Species

Literature, links & citation

Citations
  1. 2021Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 59. European Journal of Mineralogy, 33 (1) 139-143 doi:10.5194/ejm-33-139-2021 DOI: 10.5194/ejm-33-139-2021
  2. 2021Kampf, Anthony R., Cooper, Mark A., Celestian, Aaron J., Nash, Barbara P., Marty, Joe (2021) Thebaite-(NH4), (NH4,K)3Al(C2O4)(PO3OH)2(H2O), a new phosphate–oxalate mineral from the Rowley mine, Arizona, USA. Mineralogical Magazine, 85 (3) 379-386 doi:10.1180/mgm.2021.26DOI: 10.1180/mgm.2021.26
  3. 2022(2022) Thebaite-(NH4). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Thebaite-(NH4) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/thebaite-nh4-55318},
  note      = {Accessed 2026-05-11}
}