Therasiaite

(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5
IMA status
  • Approved
IMA symbol
The
IMA approved
2013
Also known as
  • IMA2013-050
  • Therasiaiet

Where it forms, where it's found

Geological setting

In a medium-temperature (~250°C) intracrater active fumarole.

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

1recorded occurrences
Source · OpenStreetMap

Physical

Colour
Brown to dark brown
Density
2.41 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.585 – 1.63
Surface relief
Moderate
Principal indices
nα 1.585 · nβ 1.615 · nγ 1.630
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cc
Cell parameters
a = 18.284(4) Å · b = 12.073(2) Å · c = 9.535(2) Å
Cell angles
β = 108.10(1) °
Ratio a:b:c
1 : 0.660 : 0.521
Unit cell volume
2000.6 ų
Z
4
Morphology

Equant to short prismatic crystals

Type-locality form

On a pyroclastic breccia as brown to dark brown equant to short prismatic crystals up to 0.1 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
26.80%
17ClChlorineChlorine535.450177.250
24.74%
26FeIronIron255.845111.690
15.59%
16SSulfurSulfur332.06096.180
13.43%
11NaSodiumSodium222.99045.980
6.42%
7NNitrogenNitrogen314.00742.021
5.87%
19KPotassiumPotassium139.09839.098
5.46%
1HHydrogenHydrogen121.00812.096
1.69%
Total716.303100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2013-050
  • Therasiaiet

In other languages

German
IMA 2013-050 · Therasiait
Italian
therasiaite

Classification

Strunz
10th ed.

7.BC.65

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.65TherasiaiteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No.17. Mineralogical Magazine, 77 (7) 2997-3005 doi:10.1180/minmag.2013.077.7.09DOI: 10.1180/minmag.2013.077.7.09
  2. 2014Demartin, F., Castellano, C., Campostrini, I. (2014) Therasiaite, (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5, a new sulfate chloride from La Fossa Crater, Vulcano, Aeolian islands, Italy. Mineralogical Magazine, 78 (1) 203-213 doi:10.1180/minmag.2014.078.1.14 DOI: 10.1180/minmag.2014.078.1.14
  3. 2015(2015) Therasiaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Therasiaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/therasiaite-43926},
  note      = {Accessed 2026-05-11}
}