Thermessaite

K2AlF3(SO4)
IMA status
  • Approved
IMA symbol
Tms
IMA approved
2007
Also known as
  • IMA2007-030
  • Thermessaiet

Where it forms, where it's found

Geological setting

An altered pyroclastic breccia in active medium- to high-temperature fumaroles at the rim of La Fossa crater.

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
colourless to white
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
None observed
Density
2.77 g/cm³

Optical

Refractive index
1.445
Surface relief
Low
Principal indices
nα 1.445
UV response
none observed under both short- and long-wave

Crystallography

Crystal system
Orthorhombic
Space group
#63
Cell parameters
a = 10.81 Å · b = 8.336 Å · c = 6.822 Å
Ratio a:b:c
1 : 0.771 : 0.631
Morphology

Prismatic with (110) and the pinacoid (100) as the dominant forms, terminated by minor (111).

Type-locality form

sharp translucent crystals up to 0.25 mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
19KPotassiumPotassium239.09878.196
30.28%
8OOxygenOxygen415.99963.996
24.78%
9FFluorineFluorine318.99856.994
22.07%
16SSulfurSulfur132.06032.060
12.42%
13AlAluminiumAluminium126.98226.982
10.45%
Total258.228100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2007-030
  • Thermessaiet

In other languages

German
IMA 2007-030 · Thermessait
Italian
thermessaite

Classification

Strunz
10th ed.

3.CG.25

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CGAluminofluorides with CO3, SO4, PO4Group
  • 3.CG.25ThermessaiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2008Demartin, F., Gramaccioli, C. M., Campostrini, I., Orlandi, P. (2008) Thermessaite, K2[AlF3SO4], a new ino-aluminofluoride-sulfate from La Fossa crater, Vulcano, Aeolian Islands, Italy. The Canadian Mineralogist, 46 (3) 693-700 doi:10.3749/canmin.46.3.693 DOI: 10.3749/canmin.46.3.693
  2. 2011(2011) Thermessaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Thermessaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/thermessaite-32287},
  note      = {Accessed 2026-05-11}
}