Tiettaite

K4Na12Fe3+2Si16O41(OH)4 · 2H2O
IMA status
  • Approved
IMA symbol
Tie
Discovered
1991
IMA approved
1991
Also known as
  • IMA1991-013
  • Tiettaiet

Where it forms, where it's found

Geological setting

Occurs in unweathered (subsurface) ultra-agpaitic pegmatites.

Type locality
Rasvumchorr Mt
  1. Murmansk Oblast
  2. Russia

67.6000°, 33.9000°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Cleavage
Perfect

(100) and (010) cleavages

Fracture
Step-Like

Optical

Optical type
Biaxial (-) · 2V measured = 79° · 2V calc = 74°
Refractive index
1.53 – 1.559
Surface relief
Moderate
Principal indices
nα 1.53 – 1.532 · nβ 1.548 – 1.549 · nγ 1.559
Dispersion
r < v moderate
Michel-Lévy diagramhighlighted lineδ = 0.0280
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]280 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation280 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#50
Cell parameters
a = 29.77(1) Å · b = 11.03(2) Å · c = 17.111(5) Å
Ratio a:b:c
1 : 0.371 : 0.575
Type-locality form

Rounded friable aggregates up to 1 cm, containing acicular hairs elongated on [001] and flattened (100).

Comment

space group Cmc2, or C2mc

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4715.999751.953
42.89%
14SiSiliconSilicon1628.085449.360
25.63%
11NaSodiumSodium1222.990275.880
15.73%
19KPotassiumPotassium439.098156.392
8.92%
26FeIronIron255.845111.690
6.37%
1HHydrogenHydrogen81.0088.064
0.46%
Total1753.339100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca

Synonyms

  • IMA1991-013
  • Tiettaiet

In other languages

German
IMA 1991-013 · Tiettait
Italian
Tiettaite

Classification

Strunz
10th ed.

9.HA.90

  • 9SilicatesClass
  • 9.HUnclassified silicatesDivision
  • 9.HAWith Alkali and Alkali-earth ElementsGroup
  • 9.HA.90TiettaiteSpecies
Dana
8th ed.

78.06.04.01

  • 78Unclassified SilicatesClass
  • 78.06Unclassified silicates possible tectosilicatesType
  • 78.06.04— unnamed intermediate level —Group
  • 78.06.04.01TiettaiteSpecies

Literature, links & citation

Citations
  1. 1993Khomyakov, A.P., Pavlov, V.P., Rogacheva, D.L., Zalkind, O.A., Martynova, A.V. (1993) Tiettaite (Na,K)17FeTiSi16O29(OH)30·2H2O. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 122(1): 121-125.
  2. 1994Jambor, John L., Roberts, Andrew C., Vanko, David A. (1994) New Mineral Names. American Mineralogist, 79 (9-10) 1009-1014
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 2001(2001) Tiettaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2021Panikorovskii, T.L., Pekov, I.V., Krhizhanovaskaya, M.G., Yakovenchuk, V.N., Britvin, S.N., Gurzhiy, V.V., Bocharov, V.N., Yapaskurt, V.O., Krivovichev, S.V. (2021): Tiettaite K4Na12Fe3+Si16O41(OH)4⋅2H2O: A Mineral with a Novel Type of Microporous Heteropolyhedral Framework. Crystallography Reports: 66: 76-85.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tiettaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tiettaite-3959},
  note      = {Accessed 2026-05-11}
}