Tillmannsite

HgAg3(VO4)
IMA status
  • Approved
IMA symbol
Till
IMA approved
2001
Also known as
  • IMA2001-010
  • Tillmannsiet

Where it forms, where it's found

Geological setting

Secondary mineral at a copper deposit.

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Translucent
Colour
Red · brownish red
Streak
Brownish red
Tenacity
very brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
7.733 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
2.3 – 2.5
Surface relief
Very high
Principal indices
nω 2.3 · nε 2.5
Pleochroism
Strong

O = orange-brown; E intense red-orange.

UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.2000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2000 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2000 nm
Order4th order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#129
Cell parameters
a = 7.727 Å · c = 4.648 Å
Unit cell volume
277.5 ų
Z
2
Morphology

Pseudo-octahedral, showing the forms (111), (110), (100), (101) and minor (001).

Twinning

Occasional twinning by contact on (100).

Type-locality form

Aggregates to 0.2 mm in diameter, consisting of pseudo-octahedral crystals to 50 µm maximum dimension.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver3107.868323.604
50.63%
80HgMercuryMercury1200.592200.592
31.39%
8OOxygenOxygen415.99963.996
10.01%
23VVanadiumVanadium150.94250.942
7.97%
Total639.134100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2001-010
  • Tillmannsiet

In other languages

German
IMA 2001-010 · Tillmannsit
Italian
Tillmannsite

Classification

Strunz
10th ed.

8.AC.80

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.80TillmannsiteSpecies

Literature, links & citation

Citations
  1. 2003Sarp, Halil, Pushcharovsky, Dmitry Y.u., MacLean, Elizabeth J., Teat, Simon J., Zubkova, Natalia V. (2003) Tillmannsite, (Ag3Hg)(V,As)O4, a new mineral: its description and crystal structure. European Journal of Mineralogy, 15 (1) 177-180 doi:10.1127/0935-1221/2003/0015-0177 DOI: 10.1127/0935-1221/2003/0015-0177
  2. 2021(2021) Tillmannsite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tillmannsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tillmannsite-28901},
  note      = {Accessed 2026-05-11}
}