Toledoite

TiFeSi
IMA status
  • Approved
IMA symbol
Tld
Also known as
  • IMA2022-036
  • Toledoiet

Where it forms, where it's found

Geological setting

A high-temperature alloy phase, formed under extremely reduced conditions in melt pockets in corundum xenocrysts derived from the upper mantle beneath Mount Carmel in Israel.

Type locality
Rakefet magmatic complex
  1. Mount Carmel
  2. Kishon Mid Reach zone 2
  3. Kishon river
  4. Haifa District
  5. Israel

32.7333°, 35.0500°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Opaque
Colour
Black
Density
5.53 g/cm³

Crystallography

Crystal system
Orthorhombic
Space group
#26
Cell parameters
a = 7.00(1) Å · b = 10.83(1) Å · c = 6.29(1) Å
Ratio a:b:c
1 : 1.547 : 0.899
Z
12
Type-locality form

occurs as irregular crystals 2–16 μm in size

Comment

a rarely seen space group

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron155.84555.845
42.37%
22TiTitaniumTitanium147.86747.867
36.32%
14SiSiliconSilicon128.08528.085
21.31%
Total131.797100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2022-036
  • Toledoiet

In other languages

German
Toledoit

Classification

Strunz
10th ed.

1.BB

  • 1ElementsClass
  • 1.BMetallic Carbides, Silicides, Nitrides, Phosphides and HydridesDivision
  • 1.BBSilicidesGroup
  • 1.BBToledoiteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 68. European Journal of Mineralogy, 34 (5) 385-391 doi:10.5194/ejm-34-385-2022 DOI: 10.5194/ejm-34-385-2022
  2. 2024Ma, Chi; Cámara, Fernando; Bindi, Luca; Griffin, William L. (2024) Toledoite, TiFeSi, a New Mineral from Inclusions in Corundum Xenocrysts from Mount Carmel, Israel. Crystals, 14 (1). 96 doi:10.3390/cryst14010096DOI: 10.3390/cryst14010096
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Toledoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/toledoite-56112},
  note      = {Accessed 2026-05-11}
}