Tooeleite

Fe3+6(AsO3)4(SO4)(OH)4 · 4H2O
IMA status
  • Approved
IMA symbol
Toe
IMA approved
1990
Also known as
  • IMA1990-010
  • Tooeleiet

Where it forms, where it's found

Geological setting

From the oxidized minerals in the dump of a skarn deposit.

Type locality
U.S. Mine
  1. Gold Hill
  2. Gold Hill Mining District (Clifton Mining District)
  3. Tooele County
  4. Utah
  5. USA

40.1569°, -113.8286°

11recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Orange
Streak
orange
Cleavage
Distinct/Good

One good normal to [001]

Density
4.23 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 2 – 5° · 2V calc = 32°
Refractive index
1.94 – 2.06
Surface relief
Very high
Principal indices
nα 1.94 · nβ 2.04 – 2.05 · nγ 2.05 – 2.06
Pleochroism
Visible

Y = orange, Z = X = lemon yellow

Dispersion
r > v slight
Michel-Lévy diagramhighlighted lineδ = 0.1150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1150 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1150 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C1 2/m 1
Cell parameters
a = 8.9575 Å · b = 6.4238 Å · c = 9.791 Å
Cell angles
β = 96.032 °
Ratio a:b:c
1 : 0.717 : 1.093
Unit cell volume
560.27 ų
Z
1
Type-locality form

elongate blades up to 10 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
36.13%
26FeIronIron655.845335.070
31.52%
33AsArsenicArsenic474.922299.688
28.19%
16SSulfurSulfur132.06032.060
3.02%
1HHydrogenHydrogen121.00812.096
1.14%
Total1062.890100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • S

Synonyms

  • IMA1990-010
  • Tooeleiet

In other languages

German
IMA 1990-010 · Tooeleit
Spanish
Tooeleita
Italian
Tooeleite

Classification

Strunz
10th ed.

4.JD.15

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JDArsenites, antimonites, bismuthites; with additional anions, with H2OGroup
  • 4.JD.15TooeleiteSpecies
Dana
8th ed.

42.12.05.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.12(AB)4(XO4)3Zq·xH2OType
  • 42.12.05— unnamed intermediate level —Group
  • 42.12.05.01TooeleiteSpecies
CIM

22.3.29

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.29TooeleiteSpecies

Literature, links & citation

Citations
  1. 1992Jambor, John L. (1992) New Mineral Names. American Mineralogist, 77 (11-12) 1305-1309
  2. 1992Cesbron, Fabien P., Williams, Sidney A. (1992) Tooeleite, a new mineral from the U.S. Mine, Tooele County, Utah. Mineralogical Magazine, 56 (382) 71-73 doi:10.1180/minmag.1992.056.382.09 DOI: 10.1180/minmag.1992.056.382.09
  3. 2003Morin, Guillaume, Juillot, Farid, Casiot, Corinne, Bruneel, Odile, Personné, Jean-Christian, Elbaz-Poulichet, Françoise, Leblanc, Marc, Ildefonse, Philippe, Calas, Georges (2003) Bacterial Formation of Tooeleite and Mixed Arsenic(III) or Arsenic(V)−Iron(III) Gels in the Carnoulès Acid Mine Drainage, France. A XANES, XRD, and SEM Study. Environmental Science & Technology, 37 (9). 1705-1712 doi:10.1021/es025688pDOI: 10.1021/es025688p
  4. 2007Morin, G., Rousse, G., Elkaim, E. (2007) Crystal structure of tooeleite, Fe6(AsO3)4SO4(OH)4·4H2O, a new iron arsenite oxyhydroxy-sulfate mineral relevant to acid mine drainage. American Mineralogist, 92 (1) 193-197 doi:10.2138/am.2007.2361 DOI: 10.2138/am.2007.2361
  5. 2016Majzlan, Juraj, Dachs, Edgar, Benisek, Artur, Koch, Christian Bender, Bolanz, Ralph, Göttlicher, Jörg, Steininger, Ralph (2016) Thermodynamic properties of tooeleite, Fe63+(As3+O3)4(SO4)(OH)4·4H2O. Chemie der Erde - Geochemistry, 76 (3). 419-428 doi:10.1016/j.chemer.2016.05.001DOI: 10.1016/j.chemer.2016.05.001
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tooeleite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tooeleite-3995},
  note      = {Accessed 2026-05-11}
}