Triazolite

NaCu2(N3C2H2)2(NH3)2Cl3 · 4H2O
IMA status
  • Approved
IMA symbol
Tzl
IMA approved
2017
Also known as
  • IMA2017-025
  • Triazoliet
  • Unnamed (Na-Cu-Cl Triazolate)

Where it forms, where it's found

Geological setting

In the contact zone between altered guano and the host rock, a gabbro consisting of amphibole, plagioclase minor clinochlore and accessory chalcopyrite.

Type locality
Pabellón de Pica
  1. Chanabaya
  2. Iquique
  3. Iquique Province
  4. Tarapacá
  5. Chile

-20.9089°, -70.1381°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Deep blue
Streak
Blue
Tenacity
brittle
Cleavage
Perfect

Perfect on (001) and imperfect on (100) and (010).

The fracture across the perfect cleavage plane is uneven.

Fracture
Irregular/Uneven
Density
2.028 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 5° · 2V calc = ~0°
Refractive index
1.582 – 1.625
Surface relief
Moderate
Principal indices
nα 1.582 · nβ 1.625 · nγ 1.625
Pleochroism
Visible

Distinct, Y = violet, X = Z = greenish-blue.

Dispersion
None observed.
Extinction
X = b.
UV response
Not fluorescent.
Notes

Absorption: Y > X ≈ Z.

Michel-Lévy diagramhighlighted lineδ = 0.0430
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]430 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation430 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#44
Cell parameters
a = 19.3575(5) Å · b = 7.15718(19) Å · c = 12.5020(4) Å
Ratio a:b:c
1 : 0.370 : 0.646
Unit cell volume
1732.09 ų
Z
4
Morphology

Prismatic crystals (up to 0.1 mm × 0.15 mm × 0.75 mm); Radial aggregates. Forms include pinacoids (001), (010) and (100) and prisms {hk0} or {0kl}.

Parting
None observed.
Type-locality form

Deep blue prismatic crystals up to 0.1 mm × 0.15 mm × 0.75 mm and their radial aggregates up to 1.5 mm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
25.49%
7NNitrogenNitrogen814.007112.056
22.47%
17ClChlorineChlorine335.450106.350
21.33%
8OOxygenOxygen415.99963.996
12.83%
6CCarbonCarbon412.01148.044
9.63%
11NaSodiumSodium122.99022.990
4.61%
1HHydrogenHydrogen181.00818.144
3.64%
Total498.672100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2017-025
  • Triazoliet
  • Unnamed (Na-Cu-Cl Triazolate)

In other languages

French
Triazolite
German
IMA 2017-025 · Triazolit

Classification

Strunz
10th ed.

10.CA.50

  • 10Organic CompoundsClass
  • 10.CMiscellaneous Organic MineralsDivision
  • 10.CAMiscellaneous Organic MineralsGroup
  • 10.CA.50TriazoliteSpecies

Literature, links & citation

Citations
  1. 2017Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2017) New minerals and nomenclature modifications approved in 2017, CNMNC Newsletter No 38. Mineralogical Magazine, 81 (4) 1033-1038 doi:10.1180/minmag.2017.081.062DOI: 10.1180/minmag.2017.081.062
  2. 2018Chukanov, Nikita V., Zubkova, Natalia V., Möhn, Gerhard, Pekov, Igor V., Belakovskiy, Dmitriy I., Van, Konstantin V., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2018) Triazolite, NaCu2(N3C2H2)2(NH3)2Cl3·4H2O, a new mineral species containing 1,2,4-triazolate anion, from a guano deposit at Pabellón de Pica, Iquique Province, Chile. Mineralogical Magazine, 82 (4) 1007-1014 doi:10.1180/minmag.2017.081.088 DOI: 10.1180/minmag.2017.081.088
  3. 2021(2021) Triazolite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Košek, Filip, Němec, Ivan, Jehlička, Jan (2023) Raman study of several Cu‐bearing complex minerals from the guano deposit at Pabellón de Pica, Tarapaca region, Chile. Journal of Raman Spectroscopy, 54 (11) 1172-1182 doi:10.1002/jrs.6506DOI: 10.1002/jrs.6506
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Triazolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/triazolite-51961},
  note      = {Accessed 2026-05-11}
}