Tsugaruite

Pb28As15S50Cl
IMA status
  • Approved
IMA symbol
Tsg
IMA approved
1997
Also known as
  • IMA1997-010
  • Tsugaruiet

Where it forms, where it's found

Geological setting

Hydrothermal baryte vein

Type locality
Yunosawa mine
  1. Ikarigaseki
  2. Minamitsugaru District
  3. Aomori Prefecture
  4. Japan

40.4292°, 140.6150°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Lead-gray
Streak
Lead-gray
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
6.83 g/cm³

Optical

Pleochroism
Weak

White with a greenish tint to gray-white with a greenish tint.

Anisotropism
Weak/moderate; rotation tints of dark brownish gray at near-extinction, to dark yellowish gray, and to dark greenish gray
Bireflectance
Weak
Internal reflections
None
Tropism
Anisotropic
Reflectance R%
(33.8,34.0,19.2,19.4) 470, (31.8,31.9,18.2,19.6) 546, (31.2,31.3,17.4,19.3) 589, (30.4,30.4,16.3,18.4) 650

Crystallography

Crystal system
Orthorhombic
Space group
#37
Cell parameters
a = 8.0774(10) Å · b = 15.1772(16) Å · c = 38.129(4) Å
Ratio a:b:c
1 : 1.879 : 4.720
Unit cell volume
4674.3 ų
Z
16
Morphology

Elongate [001] and tabular on (010).

Type-locality form

Silvery lead-gray, radiating groups of elongate tabular crystals to 2 mm long and 0.04 mm wide.

Comment

Space group Pnn2 or Pnnm according to Shimizu et al. (1998). Sub-cell with halved c. However, Biagioni et al. (2020) solved the structure in the space group Pnn2 (unit cell parameters from this later study)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead28207.2005801.600
67.75%
16SSulfurSulfur5032.0601603.000
18.72%
33AsArsenicArsenic1574.9221123.830
13.12%
17ClChlorineChlorine135.45035.450
0.41%
Total8563.880100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-010
  • Tsugaruiet

In other languages

German
IMA 1997-010 · Tsugaruit
Italian
Tsugaruite
Japanese
津軽鉱

Classification

Strunz
10th ed.

2.JB.30c

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.30cTsugaruiteSpecies

Literature, links & citation

Citations
  1. 1998Shimizu, M., Miyawaki, R., Kato, A., Matsubara, S., Matsuyama, F., Kiyota, K. (1998) Tsugaruite, Pb4As2S7, a new mineral species from the Yunosawa mine, Aomori Prefecture, Japan. Mineralogical Magazine, 62 (6) 793-799 doi:10.1180/002646198548179 DOI: 10.1180/002646198548179
  2. 1999Jambor, J.L., Roberts, A.C. (1999) New mineral names. American Mineralogist: 84: 990-994.
  3. 2014Matsushita, Y., Momma, K., Miyawaki, R., Sato, A., Kaise, M, Kitazawa, H. (2014): Crystallographic examination of tsugaruite. IMA2014_ABSTRACT VOLUME.pdf, p. 331.
  4. 2019Miyawaki, Ritsuro, Hatert, Frédéric, Mills, Stuart J. (2019) New minerals and nomenclature modifications approved in 2019. CNMNC Newsletter 49. Mineralogical Magazine, 83 (3) 479-483 doi:10.1180/mgm.2019.35 DOI: 10.1180/mgm.2019.35
  5. 2020Biagioni, Cristian; Bindi, Luca; Momma, Koichi; Miyawaki, Ritsuro; Matsushita, Yoshitaka; Më, Yves (2020) Determination of the crystal structure and redefinition of tsugaruite, Pb28As15S50Cl, the first lead-arsenic chloro-sulfosalt. The Canadian Mineralogist, 59 (1). 125-137 doi:10.3749/canmin.2000005DOI: 10.3749/canmin.2000005
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tsugaruite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tsugaruite-7344},
  note      = {Accessed 2026-05-11}
}