Ungemachite

K3Na8Fe3+(SO4)6(NO3)2 · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ugm
Discovered
1936
Also known as
  • Ungemachiet

Where it forms, where it's found

Geological setting

Oxidized copper ore body in an arid region.

Oxidation zone for pyrites in arid environment.

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · pale yellow · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (0001)

Fracture
Irregular/Uneven
Density
2.287 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.449 – 1.502
Surface relief
Low
Principal indices
nω 1.502 · nε 1.449
Michel-Lévy diagramhighlighted lineδ = 0.0530
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]530 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation530 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 10.898(1) Å · c = 24.989(6) Å
Z
3
Morphology

Crystals thick tabular (0001). Forms include (0001), (1011), (0112), (1123), (1014), and many others.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
49.42%
16SSulfurSulfur632.060192.360
16.51%
11NaSodiumSodium822.990183.920
15.78%
19KPotassiumPotassium339.098117.294
10.06%
26FeIronIron155.84555.845
4.79%
7NNitrogenNitrogen214.00728.014
2.40%
1HHydrogenHydrogen121.00812.096
1.04%
Total1165.493100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ungemachiet

In other languages

German
Ungemachit
Italian
Ungemachite

Classification

Strunz
10th ed.

7.DG.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DGWith large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3Group
  • 7.DG.10UngemachiteSpecies
Dana
8th ed.

32.02.03.01

  • 32Compound SulfatesClass
  • 32.02Hydrated Compound SulfatesType
  • 32.02.03— unnamed intermediate level —Group
  • 32.02.03.01UngemachiteSpecies
CIM

25.11.11

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.11UngemachiteSpecies

Literature, links & citation

Citations
  1. 1936Peacock, M. A., Bandy, M. C. (1936) Ungemachite and clino-ungemachite: new minerals from Chile. American Mineralogist, 21 (12(part2)) 2
  2. 1938Peacock, M. A., Bandy, M. C. (1938) Ungemachite and clino-ungemachite: new minerals from Chile. American Mineralogist, 23 (5) 314-328
  3. 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1986Groat, L. A., Hawthorne, Frank C. (1986) Structure of ungemachite, K3Na8Fe3+(SO4)6(NO3)2·6H2O. American Mineralogist, 71. 826-829
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ungemachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ungemachite-4095},
  note      = {Accessed 2026-05-11}
}