Vanderheydenite

Zn6(PO4)2(SO4)(OH)4 · 7H2O
IMA status
  • Approved
IMA symbol
Vhy
IMA approved
2014
Also known as
  • IMA2014-076
  • Vanderheydeniet

Where it forms, where it's found

Geological setting

Sulfide in gneiss

Type locality
Block 14 opencut
  1. Broken Hill
  2. Broken Hill district
  3. Yancowinna Co.
  4. New South Wales
  5. Australia

-31.9591°, 141.4751°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Cleavage
None Observed
Density
3.06 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 39.8°
Refractive index
1.565 – 1.582
Surface relief
Moderate
Principal indices
nα 1.565 · nβ 1.580 · nγ 1.582
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 6.2040(12) Å · b = 19.619(4) Å · c = 7.7821(16) Å
Cell angles
β = 90.67(3) °
Ratio a:b:c
1 : 3.162 : 1.254
Unit cell volume
947.1 ų
Morphology

Pseudohexagonal blades up to 0.4 mm in length, flattened on (100) and exhibiting the forms (100), (010), and (021).

Type-locality form

Aggregates of colourless crystals up to 0.5 mm across in voids of a sphalerite–galena matrix

Comment

Space-group setting P21/n.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc665.380392.280
44.97%
8OOxygenOxygen2315.999367.977
42.18%
15PPhosphorusPhosphorus230.97461.948
7.10%
16SSulfurSulfur132.06032.060
3.67%
1HHydrogenHydrogen181.00818.144
2.08%
Total872.409100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2014-076
  • Vanderheydeniet

In other languages

German
IMA 2014-076 · Vanderheydenit
Italian
vanderheydenite

Classification

Strunz
10th ed.

8.DO.60

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DOWith CO3, SO4, SiO4Group
  • 8.DO.60VanderheydeniteSpecies

Literature, links & citation

Citations
  1. 2015Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05DOI: 10.1180/minmag.2015.079.1.05
  2. 2018Elliott, Peter, Kolitsch, Uwe (2018) Description and crystal structure of vanderheydenite, Zn6(PO4)2(SO4)(OH)4·7H2O, a new mineral from Broken Hill, New South Wales, Australia. European Journal of Mineralogy, 30 (4) 835-840 doi:10.1127/ejm/2018/0030-2750 DOI: 10.1127/ejm/2018/0030-2750
  3. 2020(2020) Vanderheydenite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vanderheydenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vanderheydenite-46520},
  note      = {Accessed 2026-05-11}
}