Vanthoffite

Na6Mg(SO4)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vhf
Discovered
1902
Also known as
  • Vanthoffiet

Where it forms, where it's found

Geological setting

Evaporite deposits

Oceanic salt deposits.

Type locality
Wilhelmshall
  1. Halberstadt
  2. Harz
  3. Saxony-Anhalt
  4. Germany

51.9617°, 10.9403°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · pearly
Transparency
Transparent
Colour
Colourless · gray · pale yellow · colourless in transmitted light
Streak
Colourless
Tenacity
fragile
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
2.694 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 83° · 2V calc = 70°
Refractive index
1.486 – 1.489
Surface relief
Low
Principal indices
nα 1.486 · nβ 1.488 · nγ 1.489
Dispersion
weak r < v
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 9.781(2) Å · b = 9.196(2) Å · c = 8.197(2) Å
Cell angles
β = 113.61(2) °
Ratio a:b:c
1 : 0.940 : 0.838
Z
2
Morphology

Massive only; anhedral grains or bedded aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
46.84%
11NaSodiumSodium622.990137.940
25.24%
16SSulfurSulfur432.060128.240
23.47%
12MgMagnesiumMagnesium124.30524.305
4.45%
Total546.469100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Vanthoffiet

In other languages

French
Vanthoffite
German
Vanthoffit
Italian
Vanthoffite
Chinese
无水钠镁矾

Classification

Strunz
10th ed.

7.AC.05

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ACWith medium-sized and large cationsGroup
  • 7.AC.05VanthoffiteSpecies
Dana
8th ed.

28.04.01.01

  • 28Anhydrous Acid and Normal SulfatesClass
  • 28.04MiscellaneousType
  • 28.04.01— unnamed intermediate level —Group
  • 28.04.01.01VanthoffiteSpecies
CIM

25.3.8

  • 25SulphatesClass
  • 25.3Sulphates of MgGroup
  • 25.3.8VanthoffiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1902Kubierschky, K. (1902) Über ein eigenthümliches Salzvorkommen im sogenannten Magdeburg-Halberstädter Becken. Sitzungsberichte der Königlich Preussischen Akademie der Wissenschaften, Berlin, Ber.: 21: 404-413.
  2. 1909Görgey, R. (1909) Salzvorkommen aus Hall in Tirol. Tschermaks Mineralogische und Petrographische Mitteilungen: 28 (4): 334-346.
  3. 1926Doelter, C. (1926) Handbuch der Mineral-chemie: 4(2): 93.
  4. 1935Ide (1935) Kali: 29: 83;...Min. Abs. (1936): 6: 351.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vanthoffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vanthoffite-4151},
  note      = {Accessed 2026-05-11}
}