Vésigniéite

Cu3Ba(VO4)2(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vsg
Also known as
  • Vesigneite
  • Vésigniéiet

Where it forms, where it's found

Geological setting

Secondary mineral formed in copper bearing uranium-vanadium deposits.

Type locality
Glücksstern Mine
  1. Gottlob Hill
  2. Friedrichroda
  3. Gotha District
  4. Thuringia
  5. Germany

50.8518°, 10.5695°

47recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellow-green · dark olive-green
Streak
Greenish
Cleavage
Perfect

Perfect on (001), imperfect (110)

Density
4.56 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60° · 2V calc = 24°
Refractive index
2.053 – 2.133
Surface relief
Very high
Principal indices
nα 2.053 · nβ 2.129 · nγ 2.133
Dispersion
r < v strong
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C1 2/m 1
Cell parameters
a = 10.255(15) Å · b = 5.898(13) Å · c = 7.718(8) Å
Cell angles
β = 116.42 °
Ratio a:b:c
1 : 0.575 : 0.753
Z
2
Morphology

Lamellar pseudohexagonal crystals, botryoidal aggregates, powdery.

Twinning

Common, polysynthetic on (001)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
32.21%
8OOxygenOxygen1015.999159.990
27.03%
56BaBariumBarium1137.327137.327
23.20%
23VVanadiumVanadium250.942101.884
17.22%
1HHydrogenHydrogen21.0082.016
0.34%
Total591.855100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Vesigneite
  • Vésigniéiet

In other languages

French
vésigniéite
German
Vésigniéit
Spanish
vesignieita
Italian
vésigniéite

Classification

Strunz
10th ed.

8.BH.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.45VésigniéiteSpecies
Dana
8th ed.

41.05.13.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.13— unnamed intermediate level —Group
  • 41.05.13.01VésigniéiteSpecies
CIM

21.1.14

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.14VésigniéiteSpecies

Literature, links & citation

Citations
  1. Johan, Z., Povondra, P. (1987): Vanadium- and copper-bearing dolomite nodules from Permian sediments near Horní kalná, Czechoslovakia. Neues Jahrbuch für Mineralogie, Abhandlungen, 157 (3), 245-266.
  2. 1955Guillemin, C. (1955) Une nouvelle espèce minéral: la vésigniéite, Cu3Ba(VO4)2(OH)2. Comptes Rendus Hebdomadaires des Séances de l’Académie des Sciences de Paris: 240: 2331-2333.
  3. 1955American Mineralogist (1955) 40: 942.
  4. 1956Guillemin, Claude (1956) Contribution à la minéralogie des arséniates, phosphates et vanadates de cuivre. II. — Phosphates et vanadates de cuivre. Bulletin de la Société française de Minéralogie et de Cristallographie, 79 (4). 219-275 doi:10.3406/bulmi.1956.5073DOI: 10.3406/bulmi.1956.5073
  5. 1976Guillemin, C. and Johan, Z. (1976) Étude radiocristallographie de la vésigniéite, Cu3Ba(VO4)2(OH)2. Compt. Rendus Acad. Sci. Paris: 282: 803–805 (in French).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vésigniéite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vesignieite-4175},
  note      = {Accessed 2026-05-11}
}