Vinciennite

Cu10Fe4SnAsS16
IMA status
  • Approved
IMA symbol
Vcn
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-031
  • Vincienniet

Where it forms, where it's found

Type locality
Chizeuil Mine
  1. Chalmoux
  2. Charolles
  3. Saône-et-Loire
  4. Bourgogne-Franche-Comté
  5. France

46.5867°, 3.8722°

16recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Orange
Tenacity
brittle
Fracture
Conchoidal
Density
4.29 g/cm³

Optical

Anisotropism
Weak; purplish blue to greenish brown-yellow
Tropism
Anisotropic
Reflectance R%
(19.4,19.4) 420, (21.8,20.6) 460, (23.9,22.8) 500, (27.7,26.5) 540, (30.7,29.5) 580, (33.6,32.1) 620, (35.9,34.3) 660, (37.8,36.0) 700
Reflected-light panel
28.9 %anisotropic · dual curve
Specimen sRGB 210, 133, 57
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak; purplish blue to greenish brown-yellow

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 10.697(6) Å · c = 10.697(6) Å
Z
2
Twinning

Simple and poor polysynthetic twins.

Type-locality form

Grains up to 1 mm

Comment

Point Group: 4/m 2/m 2/m, 4mm, or 422.; Space Group: P4/mmm, P4mm, P422, or P4122.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1063.546635.460
40.59%
16SSulfurSulfur1632.060512.960
32.77%
26FeIronIron455.845223.380
14.27%
50SnTinTin1118.710118.710
7.58%
33AsArsenicArsenic174.92274.922
4.79%
Total1565.432100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn

Synonyms

  • IMA1983-031
  • Vincienniet

In other languages

German
IMA 1983-031 · Vinciennit
Italian
Vinciennite

Classification

Strunz
10th ed.

2.CB.35a

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.35aVincienniteSpecies
Dana
8th ed.

03.01.02.01

  • 03SulfosaltsClass
  • 03.01ø > 4Type
  • 03.01.02— unnamed intermediate level —Group
  • 03.01.02.01VincienniteSpecies
CIM

6.1.14

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.1Sulphostannates and other sulfides containing SnGroup
  • 6.1.14VincienniteSpecies

Literature, links & citation

Citations
  1. 1985Cesbron, Fabien, Giraud, Roger, Picot, Paul, Pillard, François (1985) La vinciennite, Cu10Fe4Sn(As,Sb)S16, une nouvelle espèce minérale. Etude paragénétique du gîte type de Chizeuil, Saône-et-Loire. Bulletin de Minéralogie, 108 (3) 447-456 doi:10.3406/bulmi.1985.7841DOI: 10.3406/bulmi.1985.7841
  2. 1986American Mineralogist (1986) 71: 1280-1281. (Abs.)
  3. 1987Jambor, J.L., Owens, D.R. (1987): Vinciennite in the Maggie porphyry copper deposit, British Columbia. Canadian Mineralogist 25, 227-228.
  4. 1994Marcoux, E., Milési, J. P., Moëlo, Y. (1994) Vinciennite and Cu-excess tennantite from the Layo (Cu, Sn, As, Au) epithermal deposit (Southern Peru) Mineralogy and Petrology, 51 (1) 21-36 doi:10.1007/bf01164912DOI: 10.1007/bf01164912
  5. 2004Kouzmanov, K., Ramboz, C., Bailly, L., Bogdanov, K. (2004) Genesis of high sulfidation vinciennite-bearing Cu-As-Sn (±Au) assemblage from the Radka epithermal copper deposit, Bulgaria: Evidence from mineralogy and infrared microthermometry of enargite. The Canadian Mineralogist, 42 (5) 1501-1521 doi:10.2113/gscanmin.42.5.1501 DOI: 10.2113/gscanmin.42.5.1501
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vinciennite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vinciennite-4185},
  note      = {Accessed 2026-05-11}
}