Vinogradovite

Na4Ti4(Si2O6)2[(Si,Al)4O10]O4 · (H2O,Na,K)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vgd
Discovered
1956
Also known as
  • Vinogradoviet

Where it forms, where it's found

Geological setting

In nepheline syenite pegmatites.

Type locality
Lepkhe-Nel'm Mt
  1. Seidozero Lake
  2. Lovozersky District
  3. Murmansk Oblast
  4. Russia

67.8009°, 34.7332°

25recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white · pink · pink-brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

(010)

Fracture
Irregular/Uneven
Density
2.85 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 41 – 82° · 2V calc = 24 – 80°
Refractive index
1.691 – 1.818
Surface relief
High
Principal indices
nα 1.691 – 1.745 · nβ 1.769 – 1.773 · nγ 1.773 – 1.818
Pleochroism
Weak

Sometimes weakly pleochroic from colorless on X to brownish on Z.

Dispersion
r > v strong
Extinction
Y = b; X ∧ a = 7°.
UV response
White to green (UV)
Notes

Elongation positive; the plane of the optic axis is perpendicular to (010).

Michel-Lévy diagramhighlighted lineδ = 0.0775
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]775 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation775 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 24.50(1) Å · b = 8.662(2) Å · c = 5.211(20) Å
Cell angles
β = 100.13(3) °
Ratio a:b:c
1 : 0.354 : 0.213
Morphology

Prismatic crystals showing faces (010), (110), (410), (101), (_101).

Twinning

Uncommonly on (010).

Type-locality form

Spherulites and in aggregates of fibrous crystals, less commonly in cavities as fine prismatic crystals.

Comment

Cell from Kalsbeek & Rønsbo (1992). Range observed: a = 24.38-25.01, b = 8.66-8.72, c = 5.21-5.23 Å, beta = 99.50-104.43°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2915.999463.971
36.47%
14SiSiliconSilicon828.085224.680
17.66%
22TiTitaniumTitanium447.867191.468
15.05%
11NaSodiumSodium722.990160.930
12.65%
19KPotassiumPotassium339.098117.294
9.22%
13AlAluminiumAluminium426.982107.928
8.48%
1HHydrogenHydrogen61.0086.048
0.47%
Total1272.319100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Nb
  • Mg
  • Ca
  • Ba

Synonyms

  • Vinogradoviet

In other languages

German
Vinogradovit
Italian
Vinogradovite
Chinese
白钛硅钠石

Classification

Strunz
10th ed.

9.DB.25

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DBInosilicates with 2-periodic single chains, Si2O6; Pyroxene-related mineralsGroup
  • 9.DB.25VinogradoviteSpecies
Dana
8th ed.

68.01.02.01

  • 68Inosilicates Structures with Chains of More Than One WidthClass
  • 68.01Structures with Chains of More Than One WidthType
  • 68.01.02— unnamed intermediate level —Group
  • 68.01.02.01VinogradoviteSpecies
CIM

16.14.2

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.14Aluminosilicates of Ti, Zr, Sn and PbGroup
  • 16.14.2VinogradoviteSpecies

Literature, links & citation

Citations
  1. 1956Semenov, E.I., Bohnshtedt-Kupletskaya, E.M., Moleva, V.A., Sludskaya, N.N. (1956) Vinogradovite - a new mineral. Doklady Akademii Nauk SSSR: 109: 617-620 (in Russian).
  2. 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (3-4). 307-308
  3. 1968Rastsvetaeva, R.K., Simonov, V.I., Belov, N.V. (1968) Crystal structure of vinogradovite Na4Ti4[Si2O6]2[Si4O10]O4·nH2O. Soviet Physics - Doklady: 12: 1090-1092.
  4. 1984Rastsvetaeva, R.K., Andrianov, V.I. (1984) Refined crystal structure of vinogradovite. Soviet Physics, Crystallography: 29(4): 403-406.
  5. 1986Karup-Møller, S. (1986) Murmanite from the Ilímaussaq alkaline complex, South Greenland. Neues Jahrbuch für Mineralogie - Abhandlungen: 155: 67-88.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vinogradovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vinogradovite-4186},
  note      = {Accessed 2026-05-11}
}