Vladimirite

Ca4(AsO4)2(AsO3OH) · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vld
Discovered
1953
Also known as
  • Vladimiriet

Where it forms, where it's found

Type locality
Khovu-Aksy Ni-Co deposit
  1. Chedi-Kholsky District
  2. Tuva
  3. Russia

51.1597°, 93.6858°

13recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Usually colorless to white · also pale rose
Streak
White
Tenacity
brittle
Density
3.12 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70° · 2V calc = 76 – 84°
Refractive index
1.65 – 1.661
Surface relief
High
Principal indices
nα 1.650 – 1.651 · nβ 1.654 – 1.656 · nγ 1.656 – 1.661
Birefringence
0.008
Pleochroism
Non-pleochroic
Dispersion
r > v strong
Extinction
Z ^ c = 37°
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 5.81 Å · b = 10.19 Å · c = 22.7 Å
Cell angles
β = 97.32 °
Ratio a:b:c
1 : 1.754 : 3.907
Z
3
Morphology

Acicular to bladed crystals in open radial clusters.

Type-locality form

Acicular, radial aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
39.37%
33AsArsenicArsenic374.922224.766
34.57%
20CaCalciumCalcium440.078160.312
24.66%
1HHydrogenHydrogen91.0089.072
1.40%
Total650.134100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Vladimiriet

In other languages

German
Vladimirit
Italian
Vladimirite

Classification

Strunz
10th ed.

8.CJ.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.25VladimiriteSpecies
Dana
8th ed.

39.02.02.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.02— unnamed intermediate level —Group
  • 39.02.02.01VladimiriteSpecies
CIM

20.2.10

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.10VladimiriteSpecies

Literature, links & citation

Citations
  1. 1953Nefedov, E.I. (1953) Report on new minerals discovered by him p.317 in V. A. Mokievsky. The scientific session of the Federov Institute together with the All-Union Mineralogical Society. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 82(4): 311-317.
  2. 1955Fleischer, M. (1955) New mineral names. American Mineralogist, 40 (5-6). 551-554
  3. 1956Fleischer, M. (1956) New mineral names. American Mineralogist, 41 (7-8). 671-674
  4. 1964Pierrot, Roland (1964) Contribution à la minéralogie des arséniates calciques et calcomagnésiens naturels. Bulletin de Minéralogie, 87 (2) 169-211 doi:10.3406/bulmi.1964.5727DOI: 10.3406/bulmi.1964.5727
  5. 1965Fleischer, Michael (1965) New Mineral Names. American Mineralogist, 50 (5-6) 805-813
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vladimirite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vladimirite-4195},
  note      = {Accessed 2026-05-11}
}