Vladkrivovichevite

[Pb32O18][Pb4Mn2O]Cl14(BO3)8 · 2H2O
IMA status
  • Approved
IMA symbol
Vkv
IMA approved
2011
Also known as
  • IMA2011-020
  • Vladkrivovicheviet
  • Vladkrivovichit
  • +1 more

Where it forms, where it's found

Geological setting

Late-stage products of hydrothermal reworking of primary sulfide minerals.

Type locality
Kombat Mine
  1. Kombat
  2. Otavi Constituency
  3. Otjozondjupa Region
  4. Namibia

-19.7081°, 17.7033°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Colour
Pale greenish yellow
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
7.40 g/cm³

Optical

Optical colour
Bluish grey
Anisotropism
Weak
Bireflectance
Weak
Internal reflections
Colorless
Tropism
Anisotropic
Reflectance R%
(22.0,23.2) 400, (19.5,20.2) 420, (18.4,19.0) 440, (17.5,18.2) 460, (17.2,17.9) 470, (17.0,17.7) 480, (16.6,17.2) 500, (16.1,16.7) 520, (15.8,16.3) 540, (15.7,16.3) 546, (15.6,16.2) 560, (15.6,16.2) 580, (15.5,16.1) 589, (15.5,16.1) 600, (15.4,16.0) 620, (15.3,16.0) 640, (15.4,16.1) 650, (15.4,16.2) 660, (15.7,16.8) 680, (16.2,17.7) 700
Notes

The mean RIs in air at 589 nm calculated from the Fresnel equation (assuming k = 0) are 2.30 and 2.34

Reflected-light panel
16.6 %anisotropic · dual curve
Specimen sRGB 146, 102, 60
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak
Anisotropism
Weak
Reflected colour
Bluish grey
Internal reflections
Colorless

Crystallography

Crystal system
Orthorhombic
Space group
Pmmn
Cell parameters
a = 12.759(1) Å · b = 27.169(4) Å · c = 11.515(1) Å
Ratio a:b:c
1 : 2.129 : 0.903
Z
2
Parting
none
Type-locality form

As grains <0.1 mm in size within the granular groundmass.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead36207.2007459.200
84.04%
8OOxygenOxygen4515.999719.955
8.11%
17ClChlorineChlorine1435.450496.300
5.59%
25MnManganeseManganese254.938109.876
1.24%
5BBoronBoron810.81086.480
0.97%
1HHydrogenHydrogen41.0084.032
0.05%
Total8875.843100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-020
  • Vladkrivovicheviet
  • Vladkrivovichit
  • Vladkrivovichite

In other languages

German
IMA 2011-020 · Vladkrivovichevit
Italian
Vladkrivovichevite

Classification

Strunz
10th ed.

3.DC.55

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.55VladkrivovicheviteSpecies

Literature, links & citation

Citations
  1. 2011Siidra, O., Krivovichev, S. (2011) Fascinating structural and topological complexity of oxocentered units in divalent lead natural and synthetic oxyhalides, in Joint Meeting of the DGK, DMG and ÖMG, Salzburg, Austria. Joint Meeting of the DGK, DMG and ÖMG, Salzburg, Austria, Oldenbourg Verlag. Munich, Germany. 32
  2. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  3. 2012Turner, R., Siidra, O. I., Rumsey, M. S., Krivovichev, S. V., Stanley, C. J., Spratt, J. (2012) Hereroite and vladkrivovichevite: two novel lead oxychlorides from the Kombat mine, Namibia. Mineralogical Magazine, 76 (4) 883-890 doi:10.1180/minmag.2012.076.4.05 DOI: 10.1180/minmag.2012.076.4.05
  4. 2013Siidra, O. I., Krivovichev, S. V., Turner, R. W., Rumsey, M. S., Spratt, J. (2013) Crystal chemistry of layered Pb oxychloride minerals with PbO-related structures: Part II. Crystal structure of vladkrivovichevite, [Pb32O18][Pb4Mn2O]Cl14(BO3)8·2H2O. American Mineralogist, 98 (1) 256-261 doi:10.2138/am.2013.4244DOI: 10.2138/am.2013.4244
  5. 2015(2015) Vladkrivovichevite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vladkrivovichevite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vladkrivovichevite-42043},
  note      = {Accessed 2026-05-11}
}