Vlodavetsite

Ca2Al(SO4)2F2Cl · 4H2O
IMA status
  • Approved
IMA symbol
Vlo
IMA approved
1993
Also known as
  • IMA1993-023
  • Vlodavetsiet

Where it forms, where it's found

Type locality
Second scoria cone
  1. Northern Breakthrough (North Breach)
  2. Great Fissure eruption (Main Fracture)
  3. Tolbachik Volcanic field
  4. Milkovsky District
  5. Kamchatka Krai
  6. Russia

55.6878°, 160.2435°

2recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Transparent
Colour
Colourless
Tenacity
flexible
Cleavage
Perfect

(100)

Density
2.22 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.509 – 1.526
Surface relief
Moderate
Principal indices
nω 1.509 · nε 1.526
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#135
Cell parameters
a = 6.870(1) Å · c = 13.342(2) Å
Z
2
Type-locality form

Square to rectangular, tabular to scaly crystals, to 0.3 mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
43.17%
20CaCalciumCalcium240.07880.156
18.02%
16SSulfurSulfur232.06064.120
14.42%
9FFluorineFluorine218.99837.996
8.54%
17ClChlorineChlorine135.45035.450
7.97%
13AlAluminiumAluminium126.98226.982
6.07%
1HHydrogenHydrogen81.0088.064
1.81%
Total444.756100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1993-023
  • Vlodavetsiet

In other languages

German
IMA 1993-023 · Vlodavetsit
Italian
Vlodavetsite
Chinese
氯硫铝钙石

Classification

Strunz
10th ed.

7.DF.40

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.40VlodavetsiteSpecies

Literature, links & citation

Citations
  1. Volcanology and Seismology: 17: 649-660.
  2. 1995Vergasova, L.P., Filatov, S.K., Starova, G.L., Matusevich, G.L., Filasova, T.M. (1995) Vlodavetsite AlCa2(SO4)2F2Cl•4H2O – a new mineral from volcanic exhalations. Doklady Akademii Nauk SSSR: 343: 358–360. (in Russian)
  3. 1995Starova, G.L., Filatov, S.K., Matusevich, G.L., Fundamensky, V.S. (1995) The crystal structure of vlodavetsite, AlCa2(SO4)2F2Cl•4H2O. Mineralogical Magazine: 59: 159–162.
  4. 1995Vergasova, L.P., Filatov, S.K., Starova, G.L., Matusevich, G.L., Filasova, T.M. (1995) Vlodavetsite AlCa2(SO4)2F2Cl•4H2O – a new mineral from volcanic exhalations. Doklady Akademii Nauk SSSR: 343: 358–360.
  5. 1996Jambor, J.L., Pertsev, N.N., Roberts, A.C. (1996) New mineral names. American Mineralogist: 81: 766-770.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vlodavetsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vlodavetsite-7357},
  note      = {Accessed 2026-05-11}
}