Volaschioite

Fe4(SO4)O2(OH)6 · 2H2O
IMA status
  • Approved
IMA symbol
Vsh
IMA approved
2010
Also known as
  • IMA2010-005
  • Volaschioiet

Where it forms, where it's found

Geological setting

Oxidation product of pyrite in a magnetite-pyrite ore.

Type locality
Fornovolasco
  1. Fabbriche di Vergemoli
  2. Lucca Province
  3. Tuscany
  4. Italy

44.0282°, 10.3577°

3recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Yellowish orange
Streak
Orange
Tenacity
brittle
Cleavage
Perfect

Perfect on (100)

Density
3.03 g/cm³

Optical

Optical type
Biaxial
Pleochroism
Strong

Red along [010], yellowish orange normal to that direction.

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 16.085(2) Å · b = 3.054(1) Å · c = 10.929(2) Å
Cell angles
β = 93.78(1) °
Ratio a:b:c
1 : 0.190 : 0.679
Morphology

Type material: Bladed crystals elongated along [010].

Type-locality form

Radial clusters of transparent, yellowish-orange bladed crystals up to 0.1 mm long and <0.005 mm thick.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
45.76%
26FeIronIron455.845223.380
45.63%
16SSulfurSulfur132.06032.060
6.55%
1HHydrogenHydrogen101.00810.080
2.06%
Total489.506100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2010-005
  • Volaschioiet

In other languages

German
IMA 2010-005 · Volaschioit
Italian
volaschioite

Classification

Strunz
10th ed.

7.DE.62

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DEWith only medium-sized cations; unclassifiedGroup
  • 7.DE.62VolaschioiteSpecies
Dana
8th ed.

31.04.11

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.04(AB)4(XO4)Zq·xH2OType
  • 31.04.11— unnamed intermediate level —Group
  • 31.04.11VolaschioiteSpecies

Literature, links & citation

Citations
  1. 2010C. Biagioni (2010): Volaschioite (IMA 2010-005) and associated iron sulphates from the Fornovolasco mine (Apuan Alps, Tuscany, Italy). 89° Congresso SIMP.
  2. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) New minerals and nomenclature modifications approved in 2010. CNMNC Newsletter No 3. Mineralogical Magazine, 74 (3) 577-579 doi:10.1180/s0026461x00054979 DOI: 10.1180/s0026461x00054979
  3. 2011Biagioni, C., Bonaccorsi, E., Orlandi, P. (2011) Volaschioite, Fe3+4(SO4)O2(OH)6·2H2O, a new mineral from Fornovolasco, Apuan Alps, Tuscany (Italy) The Canadian Mineralogist, 49 (2) 605-614 doi:10.3749/canmin.49.2.605DOI: 10.3749/canmin.49.2.605
  4. 2013Belakovskiy D, Smith D G W, Welch M (2013) New mineral names. American Mineralogist 98, 811-815
  5. 2013(2013) Volaschioite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Volaschioite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/volaschioite-40051},
  note      = {Accessed 2026-05-11}
}