Vrbaite

Hg3Tl4As8Sb2S20
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vrb
Discovered
1912
Also known as
  • Urbaite
  • Vrbaiet

Where it forms, where it's found

Geological setting

Hydrothermal As-Tl sulfide deposit

Type locality
Allchar
  1. Ržanovo
  2. Kavadarci Municipality
  3. North Macedonia

41.1483°, 21.9536°

7recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark gray-black with bluish tint · dark red (thin fragment)
Streak
Pale yellow-red
Tenacity
brittle
Cleavage
Distinct/Good

On (010).

Fracture
Irregular/Uneven · Conchoidal
Density
5.27 g/cm³

Optical

Optical type
Biaxial (+)
Dispersion
r > v
Optical colour
Bluish-white
Internal reflections
Red
Reflectance R%
(45.8,48.6) 400, (38.2,40.6) 440, (33.8,36.7) 480, (30.8,34.0) 520, (28.6,31.1) 560, (27.6,29.2) 600, (27.1,28.8) 640, (26.6,28.4) 680, (26.4,28.0) 700
Reflected-light panel
31.7 %anisotropic · dual curve
Specimen sRGB 189, 137, 87
White reference100 % reflector under same lamp
R₁ R₂
Mode
Reflected colour
Bluish-white
Internal reflections
Red

Crystallography

Crystal system
Orthorhombic
Space group
#49
Cell parameters
a = 13.18 Å · b = 23.23 Å · c = 11.22 Å
Ratio a:b:c
1 : 1.763 : 0.851
Morphology

Small crystals, tabular (010) or pyramidal (111). Occur in groups.

Type-locality form

Small orthorhombic crystals embedded in realgar and orpiment.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
81TlThalliumThallium4204.380817.520
28.16%
16SSulfurSulfur2032.060641.200
22.08%
80HgMercuryMercury3200.592601.776
20.73%
33AsArsenicArsenic874.922599.376
20.64%
51SbAntimonyAntimony2121.760243.520
8.39%
Total2903.392100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Urbaite
  • Vrbaiet

In other languages

French
Vrbaïte
German
Vrbait
Spanish
Vrbaíta
Italian
Vrbaite

Classification

Strunz
10th ed.

2.HF.20

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HFWith SnS and PbS archetype structure unitsGroup
  • 2.HF.20VrbaiteSpecies
Dana
8th ed.

03.07.15.01

  • 03SulfosaltsClass
  • 03.07ø = 2Type
  • 03.07.15— unnamed intermediate level —Group
  • 03.07.15.01VrbaiteSpecies
CIM

5.5.10

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.5Sulpharsenites etc. of TlGroup
  • 5.5.10VrbaiteSpecies

Literature, links & citation

Citations
  1. 1912Ježek, B.(1912) Ak. Böhmen, Roz.: 21.
  2. 1912Ježek, B. (1912) Vrbait, novy thallnaty minerál z Allcharu v Macedonii. Rozpravy České Akademie: 21(26): 1-12.
  3. 1912Ježek, B. (1912) Bulletin de l'International Acadeiem des Sciences, Prague: 26: 130.
  4. 1913Křvehlík, F. (1913) XXV. Chemische Untersuchung des Vrbaits. Zeitschrift für Kristallographie-Crystalline Materials: 51(1-6): 379-383.
  5. 1913Spencer, L. J. (1913) A (sixth) list of new mineral names. Mineralogical Magazine and Journal of the Mineralogical Society, 16 (77) 352-378 doi:10.1180/minmag.1913.016.77.09 DOI: 10.1180/minmag.1913.016.77.09
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vrbaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vrbaite-4211},
  note      = {Accessed 2026-05-11}
}