Vyalsovite

CaFeAlS(OH)5
IMA status
  • Approved
IMA symbol
Vyl
Discovered
1989
IMA approved
1989
Also known as
  • IMA1989-004
  • Vyalsoviet

Where it forms, where it's found

Geological setting

In forsterite skarn at the contact of a gabbro-dolerite intrusion in dolomite.

Type locality
Komsomol'skii Mine
  1. Talnakh Cu-Ni Deposit
  2. Norilsk-Talnakh Mining Region
  3. Taimyr Peninsula
  4. Taymyrskiy Autonomous Okrug
  5. Krasnoyarsk Krai
  6. Russia

69.5360°, 88.4622°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Opaque
Colour
Carmine-red
Density
2.0 g/cm³

Optical

Tropism
Anisotropic
Reflectance R%
(10.1, 7.7) 250, (10.1, 6.8) 260, (9.9, 6.0) 270, (9.8, 5.8) 280, (9.7, 5.9) 290, (9.6, 6.5) 300, (9.5, 7.4) 310, (9.4, 8.0) 320, (9.2, 8.0) 330, (9.0, 7.6) 340, (9.0, 7.2) 350, (9.0, 6.8) 360, (8.8, 6.5) 370, (8.8, 6.5) 380, (8.6, 6.9) 390, (8.5, 8.0) 400, (8.4, 9.8) 410, (8.2, 11.5) 420, (8.2, 12.0) 430, (8.1, 11.6) 440, (8.1, 10.2) 450, (8.1, 8.9) 460, (8.1, 7.7) 470, (8.2, 6.8) 480, (8.3, 6.9) 490, (8.3, 7.8) 500, (8.3, 9.3) 510, (8.2, 10.8) 520, (8.2, 11.6) 530, (8.2, 11.4) 540, (8.1, 10.5) 550, (8.0, 9.2) 560, (8.0, 8.3) 570, (8.0, 8.2) 580, (8.0, 9.1) 590, (7.9, 11.2) 600, (7.9, 15.1) 610, (7.9, 20.0) 620, (7.9, 25.0) 630, (7.9, 29.0) 640, (7.9, 29.1) 650, (7.8, 27.9) 660, (7.8, 26.6) 670, (7.8, 25.8) 680, (7.8, 25.3) 690, (7.8, 24.7) 700, (7.8, 23.7) 710, (7.8, 22.7) 720, (7.8, 21.7) 730, (7.8, 20.7) 740, (7.8, 19.9) 750, (7.8, 19.2) 760, (7.8, 18.7) 770, (7.8, 18.2) 780, (7.8, 17.9) 790, (7.8, 17.5) 800
Notes

In isotropic (Ro) and nearly isotropic sections, vyalsovite is dark gray; Ro corresponds to the minimum reflectance. In sections parallel to the optic axis, and thus showing Ro and Re, the mineral has extreme bireflectance and reflection pleochroism (dark

Reflected-light panel
8.4 %anisotropic · dual curve
Specimen sRGB 107, 74, 38
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Monoclinic
Space group
C1m1
Cell parameters
a = 5.205 Å · b = 21.402 Å · c = 14.400 Å
Cell angles
β = 95 °
Ratio a:b:c
1 : 4.112 : 2.767
Z
8
Type-locality form

5- to 150-µm grains and veinlets.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
33.33%
26FeIronIron155.84555.845
23.27%
20CaCalciumCalcium140.07840.078
16.70%
16SSulfurSulfur132.06032.060
13.36%
13AlAluminiumAluminium126.98226.982
11.24%
1HHydrogenHydrogen51.0085.040
2.10%
Total240.000100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1989-004
  • Vyalsoviet

In other languages

German
IMA 1989-004 · Vyalsovit
Italian
Vyalsovite
Russian
вяльсовит

Classification

Strunz
10th ed.

2.FD.45

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FDWith O, OH, H2OGroup
  • 2.FD.45VyalsoviteSpecies
Dana
8th ed.

02.14.04.01

  • 02SulfidesClass
  • 02.14Hydroxysulfides and Hydrated SulfidesType
  • 02.14.04— unnamed intermediate level —Group
  • 02.14.04.01VyalsoviteSpecies
CIM

4.6

  • 4OxysulphidesClass
  • 4.6— unnamed intermediate level —Group
  • 4.6VyalsoviteSpecies

Literature, links & citation

Citations
  1. 1992Evstigneeva, Tatiana L., Genkin, Alexandr D., Sandomirskaya, Sofya M., Trubkin, Nikolaj V. (1992) Vyalsovite, a new sulfide-hydroxide of iron, calcium, and aluminum. American Mineralogist, 77 (1-2) 201-206
  2. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  3. 2005(2005) Vyalsovite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2022Soboleva, S. V., Boeva, N. M., Evstigneeva, T. E., Bortnikov, N. S. (2022) The Crystal Structure of Vyalsovite FeCаAlS(OH)5: First Example of the Commensurate Combination of Iron Sulfide and Hydroxide Layers. Doklady Earth Sciences, 503 (2) 164-167 doi:10.1134/s1028334x22040171DOI: 10.1134/s1028334x22040171
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vyalsovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vyalsovite-4219},
  note      = {Accessed 2026-05-11}
}