Waipouaite

Ca3V4+5O9[Si2O5(OH)2][Si3O7(OH)2] · 11H2O
IMA status
  • Approved
IMA symbol
Wpo
IMA approved
2020
Also known as
  • IMA2019-095
  • Waipouaiet

Where it forms, where it's found

Geological setting

in basalt as overgrowths on thompsonite-Ca and chabazite-Ca and as inclusions within calcite and okenite

Type locality
Aranga Quarry (Stone's Quarry
  1. Hood Road Quarry)
  2. Aranga
  3. Kaipara District
  4. Northland Region
  5. New Zealand

-35.7351°, 173.5798°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Dark olive green to black
Density
2.24 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 60.2°
Refractive index
1.62 – 1.628
Surface relief
Moderate
Principal indices
nα 1.620 · nβ 1.622 · nγ 1.628
Pleochroism
Visible

Pleochroism is X blue-green, Y olive green, Z olive; X > Y >> Z.

Dispersion
none observed
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 12.843(3) Å · b = 23.589(5) Å · c = 11.560(2) Å
Cell angles
β = 115.54(3) °
Ratio a:b:c
1 : 1.837 : 0.900
Z
4
Type-locality form

prismatic crystals to 0.3 mm in length

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
51.54%
23VVanadiumVanadium550.942254.710
22.79%
14SiSiliconSilicon528.085140.425
12.57%
20CaCalciumCalcium340.078120.234
10.76%
1HHydrogenHydrogen261.00826.208
2.34%
Total1117.541100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2019-095
  • Waipouaiet

In other languages

German
IMA 2019-095 · Waipouait

Classification

Strunz
10th ed.

9.HB

  • 9SilicatesClass
  • 9.HUnclassified silicatesDivision
  • 9.HBWith Ti, V, CrGroup
  • 9.HBWaipouaiteSpecies

Literature, links & citation

Citations
  1. 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 53. European Journal of Mineralogy, 32 (1) 209-213 doi:10.5194/ejm-32-209-2020 DOI: 10.5194/ejm-32-209-2020
  2. 2022(2022) Waipouaite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2024Elliott, Peter, Kampf, Anthony R. (2024) Waipouaite, Ca3(V4.54+V0.55+)O9[(Si2O5(OH)2][Si3O7.5(OH)1.5]·11H2O, a new polyoxovanadate mineral from the Aranga Quarry, New Zealand. American Mineralogist, 109 (5) 934-939 doi:10.2138/am-2023-9048DOI: 10.2138/am-2023-9048
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Waipouaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/waipouaite-54272},
  note      = {Accessed 2026-05-11}
}