Warikahnite

Zn3(AsO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
War
Discovered
1978
IMA approved
1978
Also known as
  • IMA1978-038
  • Warikahniet

Where it forms, where it's found

Geological setting

On corroded tennantite.

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless to light yellow
Streak
White
Cleavage
Perfect

(001) perfect, (010) and [l0O] distinct to good.

Density
4.24 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 75° · 2V calc = 66°
Refractive index
1.747 – 1.768
Surface relief
High
Principal indices
nα 1.747 · nβ 1.753 · nγ 1.768
Dispersion
r > v, (type description says none observed)
Extinction
Z ∧ a = 47° on {010}; OAP ≃ {001}.
Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.71 Å · b = 8.98 Å · c = 14.53 Å
Cell angles
α = 105.59 ° · β = 93.44 ° · γ = 108.68 °
Ratio a:b:c
1 : 1.338 : 2.165
Z
4
Morphology

Bladed subhedral crystals, elongated along [100], flattened on (010), and striated. Forms include (010), (100), (001), and {0kl}.

Type-locality form

Crystals are bladed, up to 3 x 0.5 x 0.5 mm, elongated on [100], in radiating masses.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc365.380196.140
38.46%
8OOxygenOxygen1015.999159.990
31.37%
33AsArsenicArsenic274.922149.844
29.38%
1HHydrogenHydrogen41.0084.032
0.79%
Total510.006100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1978-038
  • Warikahniet

In other languages

French
Warikahnite
German
IMA 1978-038 · Warikahnit
Spanish
Warikahnita
Italian
Warikahnite
Chinese
瓦水砷锌石

Classification

Strunz
10th ed.

8.CA.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.35WarikahniteSpecies
Dana
8th ed.

40.03.01.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.01— unnamed intermediate level —Group
  • 40.03.01.01WarikahniteSpecies
CIM

20.3.5

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.5WarikahniteSpecies

Literature, links & citation

Citations
  1. 1979Keller, Paul, Hess, Heinz, Dunn, Pete J. (1979) Warikahnit, Zn3[(H2O)2|(AsO4)2], ein neues mineral aus Tsumeb, Südwestafrika. Neues Jahrbuch für Mineralogie - Monatshefte, 1979. 389-395
  2. 1980Fleischer, Michael, Cabri, Louis J., Pabst, Adolf (1980) New Mineral Names. American Mineralogist, 65 (3-4) 406-408
  3. 1980Riffel, H., Keller, P., Hess, H. (1980) Die Kristallstruktur von Warikahnit, Zn3[(H2O)2|(AsO4)2]. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 27 (3). 187-199 doi:10.1007/bf01082368DOI: 10.1007/bf01082368
  4. 2005(2005) Warikahnite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Warikahnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/warikahnite-4244},
  note      = {Accessed 2026-05-11}
}