Warwickite

(Mg,Ti,Fe,Cr,Al)2O(BO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wwk
Discovered
1838
Also known as
  • Enceladite
  • Warwickiet

Where it forms, where it's found

Geological setting

Occurs in a metamorphosed, crystalline, Precambrian marble (the Franklin Marble).

Type locality
Warwick
  1. Town of Warwick
  2. Orange County
  3. New York
  4. USA

41.2564°, -74.3603°

16recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark brown · grey to black · coppery tinge on cleavage at times · reddish brown in transmitted light
Streak
Bluish black
Tenacity
brittle
Cleavage
Distinct/Good

On (100) good.

Fracture
Irregular/Uneven
Density
3.34 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.806 – 1.83
Surface relief
Very high
Principal indices
nα 1.806 · nβ 1.809 · nγ 1.830
Pleochroism
Visible

X = Yellow brown; Y = Reddish brown; Z = Cinnamon brown

Dispersion
relatively strong
Extinction
X = c; Y = b; Z = a.
Notes

Absorption: X > Y > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 9.14(11) Å · b = 9.40(5) Å · c = 3.07(6) Å
Ratio a:b:c
1 : 1.028 : 0.336
Z
4
Morphology

Slender prismatic crystals, terminations rounded.

Type-locality form

Small dark grey to blackish prismatic crystals in white crystalline marble

Comment

Space group Pnam (non-standard setting).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
22.85%
24CrChromiumChromium251.996103.992
21.28%
22TiTitaniumTitanium247.86795.734
19.59%
8OOxygenOxygen415.99963.996
13.09%
13AlAluminiumAluminium226.98253.964
11.04%
12MgMagnesiumMagnesium224.30548.610
9.94%
5BBoronBoron110.81010.810
2.21%
Total488.796100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cr

Synonyms

  • Enceladite
  • Warwickiet

In other languages

French
Warwickite
German
Enceladit · Warwickit
Spanish
Warwickita
Italian
Warwickite

Classification

Strunz
10th ed.

6.AB.20

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ABBO3, with additional anions; 1(D) + OH, etc.Group
  • 6.AB.20WarwickiteSpecies
Dana
8th ed.

24.02.02.01

  • 24Anhydrous BoratesClass
  • 24.02A2BO2[XO3]Type
  • 24.02.02— unnamed intermediate level —Group
  • 24.02.02.01WarwickiteSpecies
CIM

9.6.1

  • 9BoratesClass
  • 9.6Borates of Ti, Sn and TaGroup
  • 9.6.1WarwickiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1838Shephard, C.U. (1838) Notice of warwickite, a new mineral species. American Journal of Science and Arts: 34: 313-315.
  2. 1839Shepard, C.U. (1839) Analysis of warwickite. American Journal of Science: 36: 85-87.
  3. 1846Hunt, T.S. (1846) Description and analysis of a new mineral, containing titanium; with some remarks on the constitution of titaniferous minerals. American Journal of Science: 2: 30-36 (as Enceladite).
  4. 1851Hunt, T.S. (1851) On the chemical constitution of the mineral, warwickite. American Journal of Science: 11: 352-356.
  5. 1874Des Cloizeaux, A. (1874) Manuel de minéralogie. 2 volumes and Atlas, Paris. volume 2, 1 Fasc., 208pp. (1874); 2 Fasc., pp 209-544 (1874/93): 16.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Warwickite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/warwickite-4245},
  note      = {Accessed 2026-05-11}
}