Watanabeite

Cu4(As,Sb)2S5
IMA status
  • Approved
IMA symbol
Wa
Discovered
1991
IMA approved
1991
Also known as
  • IMA1991-025
  • Watanabeiet

Where it forms, where it's found

Type locality
Teine Mine
  1. Sapporo City
  2. Ishikari Subprefecture
  3. Hokkaidō Prefecture
  4. Japan

43.0917°, 141.2028°

12recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Silver-grey · lead-grey
Streak
Lead-grey
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.66 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
Grey
Anisotropism
Weak
Tropism
Anisotropic
Reflectance R%
(32.5,31.5,17.7,17.0) 470, (32.0,31.1,17.0,16.3) 546, (31.1,30.3,16.1,15.5) 589, (30.0,29.3,15.0,14.5) 650

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 14.51(1) Å · b = 13.30(1) Å · c = 17.96(1) Å
Ratio a:b:c
1 : 0.917 : 1.238
Z
16
Type-locality form

Massive silvery lead-grey ore, macroscopically indistinguishable from tetrahedrite group minerals.

Comment

Symmetry uncertain and space group unknown.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
31.47%
51SbAntimonyAntimony2121.760243.520
30.14%
16SSulfurSulfur532.060160.300
19.84%
33AsArsenicArsenic274.922149.844
18.55%
Total807.848100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1991-025
  • Watanabeiet

In other languages

German
IMA 1991-025 · Watanabeit
Italian
Watanabeite
Japanese
渡辺鉱
Chinese
渡边石

Classification

Strunz
10th ed.

2.GC.15

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GCPoly-sulfarsenitesGroup
  • 2.GC.15WatanabeiteSpecies
Dana
8th ed.

03.05.15.01

  • 03SulfosaltsClass
  • 03.052.5 < ø < 3Type
  • 03.05.15— unnamed intermediate level —Group
  • 03.05.15.01WatanabeiteSpecies

Literature, links & citation

Citations
  1. 1977Luce, F. D., Tuttle, C. L., Skinner, B. J. (1977) Studies of sulfosalts of copper: V. Phases and phase relations in the system Cu-Sb-As-S between 350° and 500°C. Economic Geology, 72 (2). 271-289 doi:10.2113/gsecongeo.72.2.271DOI: 10.2113/gsecongeo.72.2.271
  2. 1993Shimizu, M., Kato, A., Matsubara, S., Criddle, A. J., Stanley, C. J. (1993) Watanabeite, Cu4(As,Sb)2S5, a new mineral from the Teine mine, Sapporo, Hokkaido, Japan. Mineralogical Magazine, 57 (389) 643-649 doi:10.1180/minmag.1993.057.389.08 DOI: 10.1180/minmag.1993.057.389.08
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 2015Repstock, Alexander, Voudouris, Panagiotis, Kolitsch, Uwe (2015) New occurrences of watanabeite, colusite, “arsenosulvanite” and “Cu-excess” tetrahedrite-tennantite at the Pefka high-sulfidation epithermal deposit, northeastern Greece. Neues Jahrbuch für Mineralogie - Abhandlungen Journal of Mineralogy and Geochemistry, 192 (2) 135-149 doi:10.1127/njma/2015/0276DOI: 10.1127/njma/2015/0276
  5. 2021(2021) Watanabeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Watanabeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/watanabeite-4246},
  note      = {Accessed 2026-05-11}
}