Waterhouseite

Mn7(PO4)2(OH)8
IMA status
  • Approved
IMA symbol
Whs
IMA approved
2004
Also known as
  • IMA2004-035
  • Waterhouseiet

Where it forms, where it's found

Type locality
Iron Monarch Main Pit
  1. Iron Knob
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-32.7447°, 137.1395°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Orange-brown to dark brown
Streak
Yellowish brown
Tenacity
brittle
Cleavage
Perfect

on (100), indistinct on (001)

Fracture
Conchoidal
Density
3.55 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.73 – 1.738
Surface relief
High
Principal indices
nα 1.73 · nβ 1.738 · nγ 1.738
Pleochroism

X pale brownish, Y brown-yellow, Z pale brownish, with absorption Z = X > Y Optical orientation: XYZ = bac (pseudo-orthorhombic)

Dispersion
absent
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 11.364 Å · b = 5.57 Å · c = 10.455 Å
Cell angles
β = 96.61 °
Ratio a:b:c
1 : 0.490 : 0.920
Unit cell volume
657.4 ų
Z
2
Morphology

(100) (dominant), (010), (011) and (001)

Twinning

All crystals are twinned on (100) by non-merohedry.

Type-locality form

Divergent sprays of bladed crystals up to 1 mm in length and up to 20 µm in thickness.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese754.938384.566
54.12%
8OOxygenOxygen1615.999255.984
36.03%
15PPhosphorusPhosphorus230.97461.948
8.72%
1HHydrogenHydrogen81.0088.064
1.13%
Total710.562100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2004-035
  • Waterhouseiet

In other languages

German
IMA 2004-035 · Waterhouseit
Italian
waterhouseite
Chinese
瓦特羟磷锰石

Classification

Strunz
10th ed.

8.BE.85

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.85WaterhouseiteSpecies

Literature, links & citation

Citations
  1. 2005Pring, A., Kolitsch, U., Birch, W. D. (2005) Description and unique crystal structure of waterhouseite, a new hydroxy manganese phosphate species from the Iron Monarch deposit, Middleback Ranges, South Australia. The Canadian Mineralogist, 43 (4) 1401-1410 doi:10.2113/gscanmin.43.4.1401 DOI: 10.2113/gscanmin.43.4.1401
  2. 2015(2015) Waterhouseite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Waterhouseite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/waterhouseite-27485},
  note      = {Accessed 2026-05-11}
}