Wheatleyite

Na2Cu(C2O4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Wty
Discovered
1984
IMA approved
1984
Also known as
  • IMA1984-040
  • Wheatleyiet

Where it forms, where it's found

Geological setting

Vein-type lead-zinc deposit.

Type locality
Wheatley Mines
  1. Schuylkill Township
  2. Chester County
  3. Pennsylvania
  4. USA

40.1056°, -75.5167°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright blue
Streak
Light blue
Tenacity
very brittle
Cleavage
Perfect

(100); two additionally observed optically.

Density
2.27 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83° · 2V calc = 84°
Refractive index
1.4 – 1.667
Surface relief
Moderate
Principal indices
nα 1.400 · nβ 1.499 · nγ 1.667
Pleochroism

X = colorless; Y = very pale blue; Z = intense dark blue.

Dispersion
none
UV response
None observed.
Michel-Lévy diagramhighlighted lineδ = 0.2670
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2670 nm5th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2670 nm
Order5th order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.559(3) Å · b = 9.665(4) Å · c = 3.589(1) Å
Cell angles
α = 76.65(2) ° · β = 103.67(2) ° · γ = 109.10(2) °
Ratio a:b:c
1 : 1.279 : 0.475
Z
1
Twinning

Sometimes observed on the single-crystal diffraction photographs, but the twin law was not determined.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
49.75%
29CuCopperCopper163.54663.546
19.76%
6CCarbonCarbon412.01148.044
14.94%
11NaSodiumSodium222.99045.980
14.30%
1HHydrogenHydrogen41.0084.032
1.25%
Total321.592100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1984-040
  • Wheatleyiet

In other languages

German
IMA 1984-040 · Wheatleyit
Italian
Wheatleyite

Classification

Strunz
10th ed.

10.AB.30

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.30WheatleyiteSpecies
Dana
8th ed.

50.01.08.01

  • 50Organic CompoundsClass
  • 50.01OxalatesType
  • 50.01.08— unnamed intermediate level —Group
  • 50.01.08.01WheatleyiteSpecies
CIM

31.1.3

  • 31Oxalates, Citrates, Mellitates and AcetatesClass
  • 31.1OxalatesGroup
  • 31.1.3WheatleyiteSpecies

Literature, links & citation

Citations
  1. 1980Gleizes, A., Maury, F., Galy, J. (1980) Crystal structure and magnetism of sodium bis(oxalato)cuprate(II)dihydrate, Na2Cu(C2O4)2.2H2O. A deductive proposal for the structure of copper oxalate, CuC2O4.xH2O (O <= x <= 1). Inorganic Chemistry, 19 (7). 2074-2078 doi:10.1021/ic50209a048DOI: 10.1021/ic50209a048
  2. 1980Chananont, P., Nixon, P. E., Waters, J. M., Waters, T. N. (1980) The structure of disodium catena-bis(μ-oxalato)-cuprate(II) dihydrate. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 36 (9) 2145-2147 doi:10.1107/s0567740880008163DOI: 10.1107/s0567740880008163
  3. 1986Rouse, R.C., Peacor, D.R., Dunn, P.J., Simmons, W.B., Newbury, D. (1986) Wheatleyite, Na2Cu(C2O4)2·2H2O, a natural sodium copper salt of oxalic acid. American Mineralogist: 71: 1240-1242.
  4. 1989Polou, R., Triche, C., Barbier, B., Pitet, G. (1989) Sodium Copper Oxalate Dihydrate: Na2Cu(C2O4)2.2H2O Synthesis, Characterization, Morphology and Optical Properties. Powder Diffraction, 4 (1). 14-18 doi:10.1017/s0885715600016237DOI: 10.1017/s0885715600016237
  5. 2005(2005) Wheatleyite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wheatleyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wheatleyite-4274},
  note      = {Accessed 2026-05-11}
}