Witzkeite

Na4K4Ca(NO3)2(SO4)4 · 2H2O
IMA status
  • Approved
IMA symbol
Wzk
IMA approved
2011
Also known as
  • IMA2011-084
  • Witzkeiet

Where it forms, where it's found

Geological setting

The oxidation zone of a guano mining field

Type locality
Punta de Lobos
  1. Iquique
  2. Iquique Province
  3. Tarapacá
  4. Chile

-21.0240°, -70.1764°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

on (001).

Fracture
Irregular/Uneven
Density
2.40 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 50 – 70° · 2V calc = 74°
Refractive index
1.47 – 1.51
Surface relief
Low
Principal indices
nα 1.470 · nβ 1.495 · nγ 1.510
Dispersion
Weak.
Extinction
X = b; Y ~ a; Z = c.
Michel-Lévy diagramhighlighted lineδ = 0.0400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]400 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation400 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 24.902(2) Å · b = 5.3323(4) Å · c = 17.246(1) Å
Cell angles
β = 94.281(7) °
Ratio a:b:c
1 : 0.214 : 0.693
Unit cell volume
2283.6 ų
Z
4
Morphology

Tabular crystals up to 140 μm in length.

Twinning

Twinning not observed.

Parting
None
Type-locality form

Tabular crystals up to 140 μm in length

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
46.11%
19KPotassiumPotassium439.098156.392
18.78%
16SSulfurSulfur432.060128.240
15.40%
11NaSodiumSodium422.99091.960
11.04%
20CaCalciumCalcium140.07840.078
4.81%
7NNitrogenNitrogen214.00728.014
3.37%
1HHydrogenHydrogen41.0084.032
0.49%
Total832.692100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-084
  • Witzkeiet

In other languages

German
IMA 2011-084 · Witzkeit
Italian
witzkeite

Classification

Strunz
10th ed.

7.DG.60

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DGWith large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3Group
  • 7.DG.60WitzkeiteSpecies

Literature, links & citation

Citations
  1. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 12. Mineralogical Magazine, 76 (1) 151-155 doi:10.1180/minmag.2012.076.1.151 DOI: 10.1180/minmag.2012.076.1.151
  2. 2012Nestola, F., Camara, F., Chukanov, N. V., Atencio, D., Coutinho, J. M. V., Contreira Filho, R. R., Farber, G. (2012) Witzkeite: A new rare nitrate-sulphate mineral from a guano deposit at Punta de Lobos, Chile. American Mineralogist, 97 (10) 1783-1787 doi:10.2138/am.2012.4109DOI: 10.2138/am.2012.4109
  3. 2017(2017) Witzkeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Witzkeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/witzkeite-42408},
  note      = {Accessed 2026-05-11}
}