Woodruffite

Zn2(Mn4+,Mn3+)5O10 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wdr
Discovered
1953
Also known as
  • Woodruffiet

Where it forms, where it's found

Geological setting

Deeply weathered manganese-zinc minerals from a zinc silicate and zinc oxide deposit hosted by marble.

Type locality
Passaic pit (Marshall Mine
  1. Passaic Mine)
  2. Sterling Hill
  3. Ogdensburg
  4. Sussex County
  5. New Jersey
  6. USA

41.0825°, -74.6061°

24recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark brown to black
Streak
Dark brown
Tenacity
brittle
Fracture
Conchoidal · Sub-Conchoidal
Density
4.01 g/cm³

Optical

UV response
Not fluorescent in ultraviolet

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 24.81 Å · b = 2.85 Å · c = 9.58 Å
Cell angles
β = 93.85 °
Ratio a:b:c
1 : 0.115 : 0.386
Unit cell volume
676 ų
Z
1
Type-locality form

Botryoidal with fine-grained internal structure may show concentric layers.

Comment

Pseudo-tetragonal (primitive); a ~8.42, c ~9.28 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese1054.938549.380
60.23%
8OOxygenOxygen1415.999223.986
24.56%
30ZnZincZinc265.380130.760
14.33%
1HHydrogenHydrogen81.0088.064
0.88%
Total912.190100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Woodruffiet

In other languages

German
Woodruffit
Italian
Woodruffite
Chinese
纤锌锰矿

Classification

Strunz
10th ed.

4.FL.25

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FLHydroxides with H2O +- (OH); sheets of edge-sharing octahedraGroup
  • 4.FL.25WoodruffiteSpecies
Dana
8th ed.

07.08.01.02

  • 07Multiple OxidesClass
  • 07.08AB3X7Type
  • 07.08.01— unnamed intermediate level —Group
  • 07.08.01.02WoodruffiteSpecies
CIM

7.5.9

  • 7Oxides and HydroxidesClass
  • 7.5Oxides of Zn, Cd and HgGroup
  • 7.5.9WoodruffiteSpecies

Literature, links & citation

Citations
  1. 1953Frondel, Clifford (1953) New manganese oxides: hydrohausmannite and woodruffite. American Mineralogist, 38 (9-10) 761-769
  2. 1963Naganna, C., Bouška, Vl. (1963) X-ray study of woodruffite from Sandur ore deposits, Mysore State, India. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (261) 506-507 doi:10.1180/minmag.1963.033.261.07 DOI: 10.1180/minmag.1963.033.261.07
  3. 1993Meisser, N., Perseil, E. A. (1993): Présence de woodruffite, (Zn, Mn+2)Mn3+4O7 . 1-2 H2O, d'hetaerolite, ZnMn2O4, et d'hydrohetaerolite, HZnMn2-xO4, dans un skarn du Mont Chemin (Valais, Suisse). Schweiz. Mineral. Petrogr. Mitt. 73, 11-19.
  4. 2003Post, Jeffrey E., Heaney, Peter J., Cahill, Christopher L., Finger, Larry W. (2003) Woodruffite: A new Mn oxide structure with 3 × 4 tunnels. American Mineralogist, 88 (11) 1697-1702 doi:10.2138/am-2003-11-1209 DOI: 10.2138/am-2003-11-1209
  5. 2021(2021) Woodruffite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Woodruffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/woodruffite-4312},
  note      = {Accessed 2026-05-11}
}