Woodwardite

(Cu1-xAlx)(SO4)x/2(OH)2 · nH2O (x < 0.5, n < 3x/2)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wwd
Discovered
1866
Also known as
  • Woodwardiet

Where it forms, where it's found

Geological setting

secondary mineral in the oxidized zone of copper deposits

Type locality
Cornwall
  1. England
  2. UK
53recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Greenish-blue · turquoise-blue
Streak
Pale blue
Density
2.38 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.552 – 1.576
Surface relief
Moderate
Principal indices
nα 1.552 – 1.571 · nβ 1.555 – 1.574 · nγ 1.565 – 1.576
Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.0090
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]90 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation90 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
R-3m
Cell parameters
a = 5.306(2) Å · c = 26.77(2) Å
Morphology

Occurs as minute, botryoidal concretions with a fine-fibrous structure; spherulitic.

Type-locality form

Stalactitic forms consisting of minute botryoidal aggregations. Crusts a couple millimeters in thickness, possessing the peculiar rippled appearance. Without traces of crystalline structure.

Synonyms

  • Woodwardiet

In other languages

German
Woodwardit
Spanish
Woodwardita
Italian
woodwardite

Classification

Strunz
10th ed.

7.DD.35

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.35WoodwarditeSpecies
Dana
8th ed.

31.02.02.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.02(AB)6(XO4)Zq·xH2OType
  • 31.02.02Woodwardite GroupGroup
  • 31.02.02.01WoodwarditeSpecies
CIM

25.2.21

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.21WoodwarditeSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1866Church (1866) Chemical News and Journal of Industrial Science, London: 13: 85, 113.
  2. 1866Church, A.H. (1866) Chemical researches on new and rare Cornish minerals. Journal of the Chemical Society: 19: 130-135.
  3. 1921Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 98. (langite, no. 3, from Klausen).
  4. 1940Meixner, H. (1940) Uber Woodwardit aus Cornwall und von Klausen (hier falschlich “Langit” gennant) in Sudtirol. Zentr. Miner. Abt. A, 11, 238–244.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Woodwardite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/woodwardite-4314},
  note      = {Accessed 2026-05-11}
}