Wooldridgeite

Na2CaCu2+2(P2O7)2 · 10H2O
IMA status
  • Approved
IMA symbol
Woo
Discovered
1989
IMA approved
1997
Also known as
  • IMA1997-037
  • Wooldridgeiet
  • Woolridgeit
  • +2 more

Where it forms, where it's found

Type locality
Judkins Quarry
  1. Nuneaton and Bedworth
  2. Warwickshire
  3. England
  4. UK

52.5333°, -1.4897°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Blue-green
Streak
Very pale blue
Density
2.279 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 76° · 2V calc = 72°
Refractive index
1.508 – 1.517
Surface relief
Moderate
Principal indices
nα 1.508 · nβ 1.511 · nγ 1.517
Pleochroism
Non-pleochroic
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0090
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]90 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation90 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#23
Cell parameters
a = 11.938(1) Å · b = 32.854(2) Å · c = 11.017(1) Å
Ratio a:b:c
1 : 2.752 : 0.923
Unit cell volume
4321.2 ų
Z
8
Morphology

Crystals have a rhombic-dipyramidal form, sometimes with subtly curved faces.

Type-locality form

Pale-blue crystals up to 2 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
51.80%
29CuCopperCopper263.546127.092
17.15%
15PPhosphorusPhosphorus430.974123.896
16.72%
11NaSodiumSodium222.99045.980
6.20%
20CaCalciumCalcium140.07840.078
5.41%
1HHydrogenHydrogen201.00820.160
2.72%
Total741.182100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-037
  • Wooldridgeiet
  • Woolridgeit
  • Woolridgeita
  • Woolridgeite

In other languages

German
IMA 1997-037 · Wooldridgeit
Italian
Wooldridgeite

Classification

Strunz
10th ed.

8.FC.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FCPolyphosphates, etc., with H2O onlyGroup
  • 8.FC.25WooldridgeiteSpecies

Literature, links & citation

Citations
  1. 1999Cooper, M. A., Hawthorne, F. C. (1999) The crystal structure of wooldridgeite, Na2CaCu2+2(P2O7)2(H2O)10, a novel copper pyrophosphate mineral. The Canadian Mineralogist, 37 (1) 73-81
  2. 1999Hawthorne, F. C., Cooper, M. A., Green, D. I., Starkey, R. E., Roberts, A. C., Grice, J. D. (1999) Wooldridgeite, Na2CaCu2+2(P2O7)2(H2O)10: A new mineral from Judkins Quarry, Warwickshire, England. Mineralogical Magazine, 63 (1) 13-16 doi:10.1180/002646199548268 DOI: 10.1180/002646199548268
  3. 2005(2005) Wooldridgeite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2019 Plant, Steve (2019) Synthetic Wooldridgeite from Calgon Cleaning Agent - A Man-made mineral? Russell Society Newsletter, 74, 24.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wooldridgeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wooldridgeite-7371},
  note      = {Accessed 2026-05-11}
}