Wulffite

K3NaCu4O2(SO4)4
IMA status
  • Approved
IMA symbol
Wlf
IMA approved
2013
Also known as
  • IMA2013-035
  • Wulffiet

Where it forms, where it's found

Geological setting

incrustations on (1) basaltic scoria, (2) tenorite or (3) aphthitalite

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark green with bluish hue or deep emerald-green.
Streak
Light green
Cleavage
Perfect

2 perfect cleavages || elongation; additional one, coplanar to (010)

Fracture
Step-Like
Density
3.23 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 58°
Refractive index
1.582 – 1.715
Surface relief
Moderate
Principal indices
nα 1.582 · nβ 1.610 · nγ 1.715
Pleochroism
Strong

emerald-green (Z), medium-saturation green (Y), Z > Y

Michel-Lévy diagramhighlighted lineδ = 0.1330
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1330 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1330 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 14.2810(6) Å · b = 4.9478(2) Å · c = 24.113(1) Å
Ratio a:b:c
1 : 0.346 : 1.688
Unit cell volume
1703.79 ų
Z
4
Morphology

coarse prismatic crystals up to 1.2 × 2 mm, in clusters and crusts; [010] elongation

Type-locality form

prisms

Comment

Space group is Pn21a

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
35.52%
29CuCopperCopper463.546254.184
31.35%
16SSulfurSulfur432.060128.240
15.82%
19KPotassiumPotassium339.098117.294
14.47%
11NaSodiumSodium122.99022.990
2.84%
Total810.690100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Rb
  • Cs

Synonyms

  • IMA2013-035
  • Wulffiet

In other languages

German
IMA 2013-035 · Wulffit
Italian
wulffite

Classification

Strunz
10th ed.

7.BC.60

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.60WulffiteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No.17. Mineralogical Magazine, 77 (7) 2997-3005 doi:10.1180/minmag.2013.077.7.09DOI: 10.1180/minmag.2013.077.7.09
  2. 2014Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018 DOI: 10.3749/canmin.1400018
  3. 2016(2016) Wulffite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wulffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wulffite-43897},
  note      = {Accessed 2026-05-11}
}