Xenophyllite

Na4Fe7(PO4)6
IMA status
  • Approved
IMA symbol
Xp
IMA approved
2006
Also known as
  • IMA2006-006
  • Xenophylliet

Where it forms, where it's found

Geological setting

Phosphide-phosphate assemblages confined to troilite nodules in metallic meteorites

Type locality
Augustinovka meteorite
  1. Zaporizhzhia Raion
  2. Zaporizhia Oblast
  3. Ukraine

48.0667°, 35.0833°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bluish-green to grey-green
Streak
White
Cleavage
Perfect

(010)

Density
3.58 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 10 – 20°
Refractive index
1.675 – 1.681
Surface relief
High
Principal indices
nα 1.675 · nβ 1.681 · nγ 1.681
Pleochroism
Visible

yellow-green (X) to dark grey-green (Z).

Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.643 Å · b = 9.633 Å · c = 17.645 Å
Cell angles
α = 88.26 ° · β = 88.16 ° · γ = 64.83 °
Ratio a:b:c
1 : 0.999 : 1.830
Z
3
Twinning

on (111)

Type-locality form

Tiny lamella up to 0.15 mm long cross-cutting millimeter-sized grains of sarcopside. Elongated lamellar inclusions up to 20 × 150 μm

Comment

Space group P1 or P-1. Xenophyllite crystals are substantially curved and twinned on (111) (in triclinic setting). That results in severe X-ray reflection overlapping and precludes obtaining the single-crystal data suitable for the structure refinement.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron755.845390.915
37.13%
8OOxygenOxygen2415.999383.976
36.48%
15PPhosphorusPhosphorus630.974185.844
17.65%
11NaSodiumSodium422.99091.960
8.74%
Total1052.695100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2006-006
  • Xenophylliet

In other languages

German
IMA 2006-006 · Xenophyllit
Italian
xenophyllite
Chinese
Xenophyllite

Classification

Strunz
10th ed.

8.AC.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.50XenophylliteSpecies

Literature, links & citation

Citations
  1. 2020Britvin, Sergey N., Krivovichev, Sergey V., Obolonskaya, Edita V., Vlasenko, Natalia S., Bocharov, Vladimir N., Bryukhanova, Vera V. (2020) Xenophyllite, Na4Fe7(PO4)6, an Exotic Meteoritic Phosphate: New Mineral Description, Na-ions Mobility and Electrochemical Implications. Minerals, 10 (4) 300 doi:10.3390/min10040300 DOI: 10.3390/min10040300
  2. 2022(2022) Xenophyllite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Xenophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/xenophyllite-29097},
  note      = {Accessed 2026-05-11}
}