Yukonite

Ca2Fe3+3(AsO4)3(OH)4 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Yuk
Discovered
1913
Also known as
  • Yukoniet

Where it forms, where it's found

Geological setting

Quartz-sulfide ore veins.

Commonly found as an oxidation product in tailings from arsenic rich deposits.

Type locality
Daulton Mine
  1. Windy Arm
  2. Tagish Lake
  3. Carcross
  4. Whitehorse mining district
  5. Yukon
  6. Canada

60.0189°, -134.6311°

42recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Red-brown · dark brown · nearly black · dark purple
Streak
Brown
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal · Sub-Conchoidal
Density
2.65 g/cm³

Optical

Optical type
Isotropic
Birefringence
0.0
Pleochroism
Non-pleochroic
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]0 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation0 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 19.6 Å
Morphology

Occurs in pitchy to waxy masses or earthy coatings on fractures in rock. TEM shows crude 5 nm platy shapes with (001), (100), and small (110).

Type-locality form

Black bright pitchy lumps with deep yellow to brown internal reflections. The lumps of yukonite decrepitated from the heat of handling or when submersed in water due to escape and expansion of enclosed carbon dioxide.

Comment

Poorly crystalline and frequently amorphous to X-rays. "a orth = √3a hex = 19.6 Å". Also pseudohexagonal: d(100) = 9.8 Å, ahex =11.3 Å (Nishikawa et al., 2006).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
39.77%
33AsArsenicArsenic374.922224.766
27.94%
26FeIronIron355.845167.535
20.83%
20CaCalciumCalcium240.07880.156
9.96%
1HHydrogenHydrogen121.00812.096
1.50%
Total804.533100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Yukoniet

In other languages

German
Yukonit
Spanish
Yukonita
Italian
Yukonite
Russian
Юконит

Classification

Strunz
10th ed.

8.DM.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DMWith large and medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.DM.25YukoniteSpecies
Dana
8th ed.

42.08.06.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.06— unnamed intermediate level —Group
  • 42.08.06.01YukoniteSpecies
CIM

20.9.12

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.12YukoniteSpecies

Literature, links & citation

Citations
  1. 1913Tyrell, J.B., Graham, R.P.D. (1913) Yukonite, a new hydrous arsenate of iron and calcium from Tagish Lake, Yukon Territory, Canada; with a note on the associated symplesite. Transactions of the Royal Society of Canada: 7(4): 13-18.
  2. 1966Jambor, J.L. (1966) Re-examination of yukonite. The Canadian Mineralogist: 8: 667. (abstr.)
  3. 1970The Canadian Mineralogist (1970): 8: 13-18.
  4. 1982Dunn, Pete J. (1982) New data for pitticite and a second occurrence of yukonite at Sterling Hill, New Jersey. Mineralogical Magazine, 46 (339) 261-264 doi:10.1180/minmag.1982.046.339.14 DOI: 10.1180/minmag.1982.046.339.14
  5. 1997Ross, Daphne R.; Post, Jeffrey E. (1997) New data on yukonite. Powder Diffraction, 12 (2). 113-116 doi:10.1017/s0885715600009556DOI: 10.1017/s0885715600009556
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Yukonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/yukonite-4377},
  note      = {Accessed 2026-05-11}
}