Zemannite

Mg0.5ZnFe3+(Te4+O3)3 · nH2O (3≤n≤4.5)
IMA status
  • Approved
IMA symbol
Zem
Discovered
1961
IMA approved
1968
Also known as
  • IMA1968-009
  • Zemanniet

Where it forms, where it's found

Geological setting

Tellurium deposit.

Type locality
Moctezuma Mine
  1. Moctezuma
  2. Moctezuma Municipality
  3. Sonora
  4. Mexico

29.6942°, -109.7125°

9recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Adamantine
Transparency
Transparent · Translucent
Colour
Light brown to dark brown
Streak
White
Tenacity
brittle
Density
4.36 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.85 – 1.93
Surface relief
Very high
Principal indices
nω 1.85 · nε 1.93
Pleochroism
Visible

Dichroic with ω = reddish brown and ε = yellowish brown.

UV response
Not fluorescent.
Notes

Absorption, ω > ε.

Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#75
Cell parameters
a = 9.41(2) Å · c = 7.64(2) Å
Z
2
Morphology

Prisms with bipyramidal terminations, (1010) and (1011).

Twinning

None observed.

Type-locality form

Hexagonal prisms terminated by a bipyramid. Crystals are less than 1 mm.

Comment

For a long time, the space group was assumed to be P63/m. Effenberger et al. (2023) showed it to be P3.

Crystal structure

Synonyms

  • IMA1968-009
  • Zemanniet

In other languages

French
zemannite
German
IMA 1968-009 · Zemannit
Spanish
Zemannita
Italian
Zemannite
Japanese
ゼーマン石
Chinese
水碲锌矿

Classification

Strunz
10th ed.

4.JM.05

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JMTellurites without additional anions, with H2OGroup
  • 4.JM.05ZemanniteSpecies
Dana
8th ed.

34.03.02.01

  • 34Selenites, Tellurites and SulfitesClass
  • 34.03A2(XO3)3·xH2OType
  • 34.03.02Zemannite GroupGroup
  • 34.03.02.01ZemanniteSpecies
CIM

28.3.8

  • 28Selenites, Selenates, Tellurites, and TelluratesClass
  • 28.3TelluritesGroup
  • 28.3.8ZemanniteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1961Mandarino, J. A., Williams, S. J. (1961) Five new minerals from Moctezuma, Sonora, Mexico. Science, 133 (3469) 2017 doi:10.1126/science.133.3469.2017DOI: 10.1126/science.133.3469.2017
  2. 1967Matzat, E. (1967). Die Kristalstruktur eines unbenannten zeolithartigen Telluritminerals, {Zn,Fe)2[TeO3]3)NaxH2-x•yH2O. Tschermaks mineralogische und petrographische Mitteilungen, 12, 108-117.
  3. 1969Mandarino, J.A., Matzat, E., Williams, S.J. (1969) Abstract: Zemannite, a new tellurite mineral from Moctezum, Sonora, Mexico. The Canadian Mineralogist: 10: 139-140.
  4. 1970Fleischer, M. (1970) New Mineral Names. American Mineralogist, 55 (7-8). 1444-1449
  5. 1976Mandarino, J. A., Matzat, E., Williams, S. J. (1976) Zemannite, a zinc tellurite from Moctezuma, Sonora, Mexico. The Canadian Mineralogist, 14 (3) 387-390
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zemannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zemannite-4392},
  note      = {Accessed 2026-05-11}
}