Zeophyllite

Ca13Si10O28(OH)2F8 · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Zp
Discovered
1902
Also known as
  • Knollit
  • Knollita
  • Knollite
  • +5 more

Where it forms, where it's found

Geological setting

secondary mineral from hydrothermal alteration of basalt

Type locality
Velké Březno
  1. Ústí nad Labem District
  2. Ústí nad Labem Region
  3. Czech Republic
18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White
Cleavage
Perfect

(0001)

Density
2.747 g/cm³

Optical

Optical type
Uniaxial (-) · 2V measured = 10°
Refractive index
1.56 – 1.577
Surface relief
Moderate
Principal indices
nω 1.565 – 1.577 · nε 1.560 – 1.569
Notes

anomalously biaxial

Michel-Lévy diagramhighlighted lineδ = 0.0065
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]65 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation65 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 9.36 Å · c = 34.48 Å
Z
9
Morphology

(Pseudo-?)hexagonal. As platy crystals in radiating spherical aggregates.

Type-locality form

radiating platy crystals, to 1 cm

Comment

Chalmers et al. (1956) give a pseudhexagonal cell with 9.34, 9.34, 13.2 Å, 90, 110, 120°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
37.31%
20CaCalciumCalcium1340.078521.014
33.75%
14SiSiliconSilicon1028.085280.850
18.19%
9FFluorineFluorine818.998151.984
9.84%
1HHydrogenHydrogen141.00814.112
0.91%
Total1543.924100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Mg
  • Na
  • K

Synonyms

  • Knollit
  • Knollita
  • Knollite
  • Radiophyllit
  • Radiophyllita
  • Radiophyllite
  • Zeophylliet
  • Zeophyllita

In other languages

German
Zeophyllit
Spanish
Ceofilita · zeofilita
Italian
zeofillite

Classification

Strunz
10th ed.

9.EE.70

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.70ZeophylliteSpecies
Dana
8th ed.

73.01.04.01

  • 73Phyllosilicates Condensed Tetrahedral SheetsClass
  • 73.01Condensed Tetrahedral Sheets with double layersType
  • 73.01.04— unnamed intermediate level —Group
  • 73.01.04.01ZeophylliteSpecies
CIM

17.1.17

  • 17Silicates Containing other AnionsClass
  • 17.1Silicates with fluoride (not containing Al)Group
  • 17.1.17ZeophylliteSpecies

Literature, links & citation

Citations
  1. 1957Dent, L.S. (1957) Zeophyllite: unit cell and transformation to cuspidine. Acta Crystallographica 10, 760-760. https://journals.iucr.org/q/issues/1957/12/00/a02158/a02158.pdf
  2. 1958Chalmers, R.A., Dent, Lesley S., Taylor, H. F. W. (1958) Zeophyllite. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (240). 726-735 doi:10.1180/minmag.1958.031.240.02DOI: 10.1180/minmag.1958.031.240.02
  3. 1972Merlino, S. (1972) The crystal structure of zeophyllite. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 28 (9) 2726-2732 doi:10.1107/s0567740872006855DOI: 10.1107/s0567740872006855
  4. 1983Passaglia, Elio, Porcelli, Cesare (1983) Zeophyllite from Monte Somma, Vesuvius, Italy. Mineralogical Magazine, 47 (344) 397-400 doi:10.1180/minmag.1983.047.344.19 DOI: 10.1180/minmag.1983.047.344.19
  5. 1997Mikenda, W.; Pertlik, F.; Povondra, P.; Ulrych, J. (1997) On zeophyllite from Radejčín, České středohoří Mts.: X-ray and IR-investigations. Mineralogy and Petrology, 61 (1). 199-209 doi:10.1007/bf01172484DOI: 10.1007/bf01172484
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zeophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zeophyllite-4396},
  note      = {Accessed 2026-05-11}
}