Zimbabweite

Na(Pb,Na,K)2(Ta,Nb,Ti)4As4O18
IMA status
  • Approved
IMA symbol
Zbb
Discovered
1984
IMA approved
1984
Also known as
  • IMA1984-034
  • Zimbabweiet

Where it forms, where it's found

Geological setting

Hydrothermally kaolinitized zone of a granitic pegmatite.

Type locality
St Anns Mine (St Anne Mine
  1. St Anne's Mine
  2. St Ann's Mine)
  3. Mwami (Miami)
  4. Karoi District
  5. Mashonaland West
  6. Zimbabwe

-16.6958°, 29.8261°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Translucent
Colour
Yellow · yellow-brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

(010)

Density
6.20 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80°
Refractive index
2.1
Surface relief
Very high
Principal indices
nα 2.10
Pleochroism
Visible

X = pale yellow-brown, Y = light reddish-brown, Z = reddish-brown

Dispersion
r < v extreme
UV response
Not fluorescent
Notes

Z = a, Y = b, X = c

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 12.245(2) Å · b = 15.287(4) Å · c = 8.664(1) Å
Ratio a:b:c
1 : 1.248 : 0.708
Z
4
Morphology

(010), (201), and less prominent (100) and (111).

Type-locality form

Honey yellow-brown euhedral to subhedral crystals, up to 1 x 1 x 2 cm.

Comment

Space Group: Ccmb.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
73TaTantalumTantalum4180.948723.792
29.71%
82PbLeadLead2207.200414.400
17.01%
41NbNiobiumNiobium492.906371.624
15.26%
33AsArsenicArsenic474.922299.688
12.30%
8OOxygenOxygen1815.999287.982
11.82%
22TiTitaniumTitanium447.867191.468
7.86%
19KPotassiumPotassium239.09878.196
3.21%
11NaSodiumSodium322.99068.970
2.83%
Total2436.120100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1984-034
  • Zimbabweiet

In other languages

German
IMA 1984-034 · Zimbabweit
Spanish
Zimbabweíta
Italian
Zimbabweite
Russian
зимбабвеит

Classification

Strunz
10th ed.

4.JA.40

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JAArsenites, antimonites, bismuthites; without additional anions, without H2OGroup
  • 4.JA.40ZimbabweiteSpecies
Dana
8th ed.

08.07.10.01

  • 08Multiple Oxides Containing Niobium, Tantalum or TitaniumClass
  • 08.07MiscellaneousType
  • 08.07.10— unnamed intermediate level —Group
  • 08.07.10.01ZimbabweiteSpecies
CIM

23.11

  • 23ArsenitesClass
  • 23.11— unnamed intermediate level —Group
  • 23.11ZimbabweiteSpecies

Literature, links & citation

Citations
  1. 1986Foord, Eugene E.; Taggart, Joseph E.; Gaines, Richard V.; Grubb, Patrick L.C.; Kristiansen, Roy (1986) Zimbabweite, a new alkali-lead-arsenic tantalate from St Anns mine, Karoi District, Zimbabwe. Bulletin de Minéralogie, 109 (4). 331-336 doi:10.3406/bulmi.1986.7943 DOI: 10.3406/bulmi.1986.7943
  2. 1988Duesler, E.N., Chakoumakos, B.C., Foord, E.E. (1988) Zimbabweite, Na(Pb,NaK)2As4(Ta,Nb,Ti)4O18, an arsenite-tantalate with a novel corner-linked octahedral sheet. American Mineralogist: 73: 1186-1190.
  3. 1990Jambor, John L., Grew, Edward S. (1990) New Mineral Names. American Mineralogist, 75 (1-2) 240-246
  4. 2005(2005) Zimbabweite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2022Cairncross, Bruce (2022) The Where of Mineral Names: Zimbabweite, St. Anne’s Mine, Mwami, Hurungwe District Mashonaland West Province, Zimbabwe. Rocks & Minerals, 97 (4) 383-386 doi:10.1080/00357529.2022.2053643DOI: 10.1080/00357529.2022.2053643
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zimbabweite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zimbabweite-4403},
  note      = {Accessed 2026-05-11}
}