Zincobotryogen

ZnFe3+(SO4)2(OH) · 7H2O
IMA status
  • Approved
IMA symbol
Zbyg
IMA approved
2016
Also known as
  • IMA2015-107

Where it forms, where it's found

Geological setting

oxidation zone of a Pb-Zn deposit

Type locality
Xitieshan Mine
  1. Xitieshan
  2. Da Qaidam (Dachaidan Co.)
  3. Haixi Mongol and Tibetan Autonomous Prefecture
  4. Qinghai
  5. China

37.3294°, 95.5675°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Greasy
Transparency
Translucent
Colour
Bright orange-red

Optical

Optical type
Biaxial (+) · 2V calc = 54.1°
Refractive index
1.542 – 1.587
Surface relief
Moderate
Principal indices
nα 1.542 · nβ 1.551 · nγ 1.587
Pleochroism
Visible

colorless (X) - light yellow (Y) - yellow (Z)

Dispersion
weak
Notes

Z ‖ b; X ∧ c = 10°; negative elongation

Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.504(2) Å · b = 17.801(4) Å · c = 7.1263(1) Å
Cell angles
β = 100.08(3) °
Ratio a:b:c
1 : 1.695 : 0.678
Unit cell volume
1311.9 ų
Z
4
Type-locality form

prismatic crystals, 0.05 to 2 mm in size

Comment

P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
56.08%
30ZnZincZinc165.38065.380
14.32%
16SSulfurSulfur232.06064.120
14.05%
26FeIronIron155.84555.845
12.24%
1HHydrogenHydrogen151.00815.120
3.31%
Total456.449100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-107

In other languages

German
IMA 2015-107 · Zincobotryogen
Italian
zincobotriogeno

Classification

Strunz
10th ed.

7.DC.25

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.25ZincobotryogenSpecies
Dana
8th ed.

31.09.06.02

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.06Botryogen GroupGroup
  • 31.09.06.02ZincobotryogenSpecies
CIM

25.5.16

  • 25SulphatesClass
  • 25.5Sulphates of Zn and HgGroup
  • 25.5.16ZincobotryogenSpecies

Literature, links & citation

Citations
  1. 1964Tu Kwang-chih, Li Hsi-lin, Hsieh Hsen-deh, and Yin Shu-sen (1964): Zincobotryogen and zincocopiapite, two new varieties of sulfate minerals. Ti Chih Hsueh Pao [Acta Geologica Sinica] 44(1), 99-101 (in Chinese with English abstract). - American Mineralogist (1964), 49, 1776 (abstract).
  2. 1988Yang Hexiong and Eu Pingqiu (1988): Crystal structure of zincobotryogen. Kuangwu Xuebao [Acta Mineralogica Sinica] 8(1), 1-12 (in Chinese with English abstract).
  3. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081DOI: 10.1180/minmag.2016.080.081
  4. 2017Yang, Zhuming, Giester, Gerald, Mao, Qian, Ma, Yuguang, Zhang, Di, Li, He (2017) Zincobotryogen, ZnFe3+(SO4)2(OH)⋅7H2O: validation as a mineral species and new data. Mineralogy and Petrology, 111 (3) 363-372 doi:10.1007/s00710-016-0484-9DOI: 10.1007/s00710-016-0484-9
  5. 2018(2018) Zincobotryogen. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zincobotryogen — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zincobotryogen-4411},
  note      = {Accessed 2026-05-11}
}